Economy & Market
Optimising Pyroprocessing with Refractories
Published
1 year agoon
By
Roshna
Refractories are vital to cement manufacturing, ensuring efficiency, durability, and sustainability in pyroprocessing. Innovations in materials, technology and recycling are transforming the industry while advancing its environmental goals.
The cement industry operates in a challenging environment of extreme temperatures, chemical reactions, and mechanical stresses, particularly during pyroprocessing. As the backbone of cement manufacturing, pyroprocessing transforms raw materials into clinker by subjecting them to temperatures of up to 1450°C. Refractories play a vital role in ensuring the efficiency, durability, and sustainability of this process by protecting equipment and enabling the process to endure hostile conditions.
This article explores the critical role of refractories in pyroprocessing, the advancements in technology improving efficiency, and the integration of sustainability in cement manufacturing through innovative refractory solutions.
Fundamentals of pyroprocessing and refractories
Pyroprocessing is a key stage in cement manufacturing, encompassing calcination, sintering, and fusion processes in high-temperature environments. The rotary kiln, the centrepiece of this stage, requires robust refractory linings to withstand extreme conditions, including high heat, abrasion, and chemical corrosion.
Refractories, crafted from materials like fireclay, high alumina, magnesia, and dolomite, form the protective shield of kilns, preheaters, and coolers. These materials are tailored to specific zones within the kiln, such as the:
- Burning zone: Magnesia-spinel and high alumina bricks are commonly used for their ability to resist extreme heat and mechanical stress.
- Preheater zone: Alumina-silicate refractories are selected for their thermal shock resistance and insulating properties.
- Cooling zone: Abrasion-resistant castables provide durability under high mechanical wear.
Mayank Gugalia, Director, Mahakoshal Refractories, says, “Our company focuses exclusively on alumina refractories, setting us apart from competitors. While others may diversify into basic refractories or flow controls, we prioritise becoming the best in the alumina segment. In terms of volume, we are among India’s largest manufacturers, and our quality standards have earned us a leading position domestically and in export markets, including the Middle East and Europe. Our commitment to sustainability further strengthens our reputation as a trusted and environmentally responsible manufacturer.”
For example, an Indian cement plant reported a 10 per cent reduction in fuel consumption after upgrading to magnesia-spinel bricks in the burning zone, demonstrating how material choices directly impact operational efficiency.
Challenges and advances in refractory performance
Refractories face multiple stressors, including:
- Chemical corrosion: Aggressive reactions from alternative fuels and raw materials can degrade linings.
- Thermal shock: Rapid temperature fluctuations can cause cracking and spalling.
- Mechanical wear: Continuous abrasion from clinker and raw materials erodes refractory surfaces.
Increased use of alternative fuels such as industrial waste adds another layer of complexity. These fuels can introduce unburned residues and chemical byproducts, accelerating refractory degradation.
Mayank Kamdar, Marketing Director, Lilanand Magnesite, says, “One of the biggest challenges in the refractory industry is the reliance on natural mineral resources. As these resources are finite, their quality can vary, which poses a challenge in ensuring consistent product quality. To address this, we explore new sources for raw materials and also develop synthetic products that offer consistent quality. By doing so, we ensure that our products meet the high standards required by our customers, even as natural resources become scarcer.”
“We are always striving to improve our products through continuous research and development. Currently, one of the key areas of focus is adapting our products to the increasing use of alternative fuels and municipal waste in cement kilns. Over the years, we have developed specialised products designed to withstand the challenging environments created by the burning of alternative fuels. For example, we offer anti-coating castables that are highly durable and suited for use in areas such as the kiln inlet, where AFR and municipal waste are burned,”
he adds.
To counter these challenges, the industry has developed advanced solutions:
- Active spinel technology: Improves resistance to slag attack and enhances thermal stability, especially in burning zones.
- Nanotechnology in refractories: Nano-bonded castables demonstrate up to 30 per cent higher strength, better insulation and resistance to thermal shocks.
- IS impregnation: This innovative method enhances density and corrosion resistance in alumina-based refractories, prolonging their lifespan.
Shreesh A Khadilkar, Consultant and Advisor, and Former Director Quality and Product Development, ACC, explains, “Reducing conditions can have substantial effects on clinker quality like problems with sulphur integration, Alite decomposition (strength reduction), conversion from C4AF to C3A (acceleration of setting), change in color of cement (from greenish grey to brownish), the detection of reducing conditions could be done using ‘Magotteaux Test’, it is important to assess the reducing conditions whether internal or peripheral, would indicate possible reasons.”
“Internal reducing conditions indicate that due to changes in liquid viscosity the larger clinker nodules are black from outside but yellow to brownish in the internal core. Such clinker nodules roll down from the transition zone with an unburnt core which disintegrates on cooling due to gamma C2S. Such nodules have high free lime, delocalised or peripheral reducing conditions due to larger size of solid AFR component (shredded size) showing CO peaks,”he adds.
For example, a cement plant using high-chrome refractories successfully transitioned to using 70 per cent alternative fuels, withstanding the increased chemical stress and maintaining operational reliability.
Role of technology in pyroprocessing
Modern technologies are revolutionising pyroprocessing by making it more efficient and precise. Key advancements include:
- Digital monitoring and IoT integration: Smart refractories embedded with sensors provide real-time data on temperature, stress and wear patterns. This enables predictive maintenance, reducing unplanned downtimes and extending the life of kiln linings.
- Simulation and modelling tools: Computational Fluid Dynamics (CFD) and thermodynamic modelling help optimise kiln design and refractory placement. These tools predict thermal loads and chemical reactions, ensuring that refractory materials are matched precisely to process requirements.
- Robotic installation: Automated systems for lining kilns ensure uniform installation, reducing human error and improving refractory performance.
- Artificial intelligence (AI): AI-driven systems analyse process data to optimise fuel usage, kiln rotation speeds, and temperature profiles, enhancing both energy efficiency and refractory durability.
“Technology plays a critical role in achieving our goals and supporting the cement industry. As I mentioned earlier, the reduction in specific refractory consumption is driven by two key factors: refining customer processes and enhancing refractory quality. By working closely as partners with our customers, we gain a deeper understanding of their evolving needs, enabling us to continuously innovate. For example, in November 2022, we established a state-of-the-art research centre in India for IFGL, something we didn’t have before,” says Arasu Shanmugam, Director and CEO India, IFGL.
“The primary objective of this centre is to leverage in-house technology to enhance the utilisation of recycled materials in manufacturing our products. By increasing the proportion of recycled materials, we reduce the depletion of natural resources and greenhouse gas emissions. In essence, our focus is on developing sustainable, green refractories while promoting circularity in our business processes. This multi-faceted approach ensures we contribute to environmental sustainability while meeting the industry’s demands,” he elaborates.
Such innovations help cement plants operate at peak efficiency, improving both productivity and sustainability.
Sustainability in cement manufacturing
The cement industry is under growing pressure to reduce its carbon footprint, and pyroprocessing plays a crucial role in achieving sustainability goals. Refractories, often overlooked in this context, are key enablers of sustainable practices.
“IKN plays a pivotal role in enhancing the operational efficiency of cement plants while aligning with global sustainability objectives. Historically, clinker coolers required frequent maintenance, with intervals as short as five to six months. This led to regular shutdowns, which disrupted operations and increased costs. With IKN’s advanced cooling solutions, cement plants can now operate their coolers for extended periods without significant maintenance. Our coolers are not only more reliable but also consume less power, which directly reduces energy costs. Additionally, the high heat recuperation efficiency of our systems ensures that less fuel is required for the cement-making process, contributing to a lower carbon footprint. Sustainability is embedded in our solutions. By reducing energy consumption, optimising processes, and minimising maintenance, we help our customers achieve their operational goals while supporting their commitment to environmental stewardship,” says Madhusudan Rasiraju, Country Head, IKN India.
Refractory recycling and circular economy: Used refractory linings are now being recycled to recover valuable raw materials like alumina and magnesia. This reduces waste and conserves natural resources. For instance, a medium-sized cement plant can recycle up to 30 per cent of its refractory waste annually, cutting down disposal costs and environmental impact.
Energy efficiency through advanced materials: High-performance refractories with low thermal conductivity reduce heat loss from kilns, improving energy efficiency. Magnesia bricks, for example, retain heat better, lowering fuel consumption by as much as 15 per cent.
Compatibility with alternative fuels: Sustainability efforts often involve transitioning to alternative fuels such as biomass and waste-derived fuels. Advanced refractory technologies are designed to withstand the chemical and thermal stresses associated with these fuels, enabling their wider adoption.
Low-carbon manufacturing of refractories: Manufacturers are now adopting eco-friendly processes to produce refractories. Innovations like solar calcination for raw materials and carbon-neutral binders are setting new benchmarks for sustainability.
“Sustainability is a key priority for us, and we have been actively engaged in decarbonisation efforts for many years. We launched our sustainability program five years ago, with a clear focus on reducing the environmental impact of our operations. Over time, we have become leaders in this space, particularly with the advent of hydrogen technology. We were one of the pioneers in the hydrogen sector, not only in developing hydrogen combustion solutions but also in the liquefaction of hydrogen for use in various industrial applications. In fact, we were the first company in India to sell a hydrogen burner, which was used for a 52-megawatt boiler application. Beyond hydrogen, we are also focused on finding alternative solid fuels for cement manufacturing. We are currently working on developing hybrid technologies that combine hydrogen, alternative solid fuels, and fossil fuels. This combination is crucial for reducing the carbon footprint in the cement industry. We are continuously investing in research and development to create innovative solutions that can accelerate the global shift toward decarbonisation,” says Rahul Rajgor, Managing Director, Fives Combustion.
By integrating these practices, the cement industry is making strides toward achieving net-zero emissions while maintaining operational efficiency.
Economic and operational impact
While refractory materials constitute only 2-3 per cent of total cement plant costs, their impact on efficiency and profitability is immense. Proper refractory selection, combined with advanced installation and maintenance techniques, can save plants hundreds of thousands of dollars annually. For example, extending the lifespan of linings in the preheater zone by six months can reduce maintenance costs by $200,000. Similarly, using high-quality castables in cooling zones has been shown to decrease clinker cooling times, boosting production output.
Conclusion
Refractories are the unsung heroes of cement manufacturing, ensuring the efficiency and resilience of pyroprocessing operations. Advances in technology and material science continue to push the boundaries of refractory performance, while sustainability initiatives are transforming how refractories are produced, used, and recycled.
As the cement industry evolves to meet global demands for efficiency and sustainability, refractories will remain at the forefront, enabling the industry to tackle its most critical challenges with innovation and precision. By prioritising high-quality materials, embracing technology and adopting sustainable practices, the cement industry can secure a future that balances profitability with environmental responsibility.
– Kanika Mathur
Concrete
Refractory demands in our kiln have changed
Published
3 days agoon
February 20, 2026By
admin
Radha Singh, Senior Manager (P&Q), Shree Digvijay Cement, points out why performance, predictability and life-cycle value now matter more than routine replacement in cement kilns.
As Indian cement plants push for higher throughput, increased alternative fuel usage and tighter shutdown cycles, refractory performance in kilns and pyro-processing systems is under growing pressure. In this interview, Radha Singh, Senior Manager (P&Q), Shree Digvijay Cement, shares how refractory demands have evolved on the ground and how smarter digital monitoring is improving kiln stability, uptime and clinker quality.
How have refractory demands changed in your kiln and pyro-processing line over the last five years?
Over the last five years, refractory demands in our kiln and pyro line have changed. Earlier, the focus was mostly on standard grades and routine shutdown-based replacement. But now, because of higher production loads, more alternative fuels and raw materials (AFR) usage and greater temperature variation, the expectation from refractory has increased.
In our own case, the current kiln refractory has already completed around 1.5 years, which itself shows how much more we now rely on materials that can handle thermal shock, alkali attack and coating fluctuations. We have moved towards more stable, high-performance linings so that we don’t have to enter the kiln frequently for repairs.
Overall, the shift has been from just ‘installation and run’ to selecting refractories that give longer life, better coating behaviour and more predictable performance under tougher operating conditions.
What are the biggest refractory challenges in the preheater, calciner and cooler zones?
• Preheater: Coating instability, chloride/sulphur cycles and brick erosion.
• Calciner: AFR firing, thermal shock and alkali infiltration.
• Cooler: Severe abrasion, red-river formation and mechanical stress on linings.
Overall, the biggest challenge is maintaining lining stability under highly variable operating conditions.
How do you evaluate and select refractory partners for long-term performance?
In real plant conditions, we don’t select a refractory partner just by looking at price. First, we see their past performance in similar kilns and whether their material has actually survived our operating conditions. We also check how strong their technical support is during shutdowns, because installation quality matters as much as the material itself.
Another key point is how quickly they respond during breakdowns or hot spots. A good partner should be available on short notice. We also look at their failure analysis capability, whether they can explain why a lining failed and suggest improvements.
On top of this, we review the life they delivered in the last few campaigns, their supply reliability and their willingness to offer plant-specific custom solutions instead of generic grades. Only a partner who supports us throughout the life cycle, which includes selection, installation, monitoring and post-failure analysis, fits our long-term requirement.
Can you share a recent example where better refractory selection improved uptime or clinker quality?
Recently, we upgraded to a high-abrasion basic brick at the kiln outlet. Earlier we had frequent chipping and coating loss. With the new lining, thermal stability improved and the coating became much more stable. As a result, our shutdown interval increased and clinker quality remained more consistent. It had a direct impact on our uptime.
How is increased AFR use affecting refractory behaviour?
Increased AFR use is definitely putting more stress on the refractory. The biggest issue we see daily is the rise in chlorine, alkalis and volatiles, which directly attack the lining, especially in the calciner and kiln inlet. AFR firing is also not as stable as conventional fuel, so we face frequent temperature fluctuations, which cause more thermal shock and small cracks in the lining.
Another real problem is coating instability. Some days the coating builds too fast, other days it suddenly drops, and both conditions impact refractory life. We also notice more dust circulation and buildup inside the calciner whenever the AFR mix changes, which again increases erosion.
Because of these practical issues, we have started relying more on alkali-resistant, low-porosity and better thermal shock–resistant materials to handle the additional stress coming from AFR.
What role does digital monitoring or thermal profiling play in your refractory strategy?
Digital tools like kiln shell scanners, IR imaging and thermal profiling help us detect weakening areas much earlier. This reduces unplanned shutdowns, helps identify hotspots accurately and allows us to replace only the critical sections. Overall, our maintenance has shifted from reactive to predictive, improving lining life significantly.
How do you balance cost, durability and installation speed during refractory shutdowns?
We focus on three points:
• Material quality that suits our thermal profile and chemistry.
• Installation speed, in fast turnarounds, we prefer monolithic.
• Life-cycle cost—the cheapest material is not the most economical. We look at durability, future downtime and total cost of ownership.
This balance ensures reliable performance without unnecessary expenditure.
What refractory or pyro-processing innovations could transform Indian cement operations?
Some promising developments include:
• High-performance, low-porosity and nano-bonded refractories
• Precast modular linings to drastically reduce shutdown time
• AI-driven kiln thermal analytics
• Advanced coating management solutions
• More AFR-compatible refractory mixes
These innovations can significantly improve kiln stability, efficiency and maintenance planning across the industry.
Concrete
Digital supply chain visibility is critical
Published
3 days agoon
February 20, 2026By
admin
MSR Kali Prasad, Chief Digital and Information Officer, Shree Cement, discusses how data, discipline and scale are turning Industry 4.0 into everyday business reality.
Over the past five years, digitalisation in Indian cement manufacturing has moved decisively beyond experimentation. Today, it is a strategic lever for cost control, operational resilience and sustainability. In this interview, MSR Kali Prasad, Chief Digital and Information Officer, Shree Cement, explains how integrated digital foundations, advanced analytics and real-time visibility are helping deliver measurable business outcomes.
How has digitalisation moved from pilot projects to core strategy in Indian cement manufacturing over the past five years?
Digitalisation in Indian cement has evolved from isolated pilot initiatives into a core business strategy because outcomes are now measurable, repeatable and scalable. The key shift has been the move away from standalone solutions toward an integrated digital foundation built on standardised processes, governed data and enterprise platforms that can be deployed consistently across plants and functions.
At Shree Cement, this transition has been very pragmatic. The early phase focused on visibility through dashboards, reporting, and digitisation of critical workflows. Over time, this has progressed into enterprise-level analytics and decision support across manufacturing and the supply chain,
with clear outcomes in cost optimisation, margin protection and revenue improvement through enhanced customer experience.
Equally important, digital is no longer the responsibility of a single function. It is embedded into day-to-day operations across planning, production, maintenance, despatch and customer servicing, supported by enterprise systems, Industrial Internet of Things (IIoT) data platforms, and a structured approach to change management.
Which digital interventions are delivering the highest ROI across mining, production and logistics today?
In a capital- and cost-intensive sector like cement, the highest returns come from digital interventions that directly reduce unit costs or unlock latent capacity without significant capex.
Supply chain and planning (advanced analytics): Tools for demand forecasting, S&OP, network optimisation and scheduling deliver strong returns by lowering logistics costs, improving service levels, and aligning production with demand in a fragmented and regionally diverse market.
Mining (fleet and productivity analytics): Data-led mine planning, fleet analytics, despatch discipline, and idle-time reduction improve fuel efficiency and equipment utilisation, generating meaningful savings in a cost-heavy operation.
Manufacturing (APC and process analytics): Advanced Process Control, mill optimisation, and variability reduction improve thermal and electrical efficiency, stabilise quality and reduce rework and unplanned stoppages.
Customer experience and revenue enablement (digital platforms): Dealer and retailer apps, order visibility and digitally enabled technical services improve ease of doing business and responsiveness. We are also empowering channel partners with transparent, real-time information on schemes, including eligibility, utilisation status and actionable recommendations, which improves channel satisfaction and market execution while supporting revenue growth.
Overall, while Artificial Intelligence (AI) and IIoT are powerful enablers, it is advanced analytics anchored in strong processes that typically delivers the fastest and most reliable ROI.
How is real-time data helping plants shift from reactive maintenance to predictive and prescriptive operations?
Real-time and near real-time data is driving a more proactive and disciplined maintenance culture, beginning with visibility and progressively moving toward prediction and prescription.
At Shree Cement, we have implemented a robust SAP Plant Maintenance framework to standardise maintenance workflows. This is complemented by IIoT-driven condition monitoring, ensuring consistent capture of equipment health indicators such as vibration, temperature, load, operating patterns and alarms.
Real-time visibility enables early detection of abnormal conditions, allowing teams to intervene before failures occur. As data quality improves and failure histories become structured, predictive models can anticipate likely failure modes and recommend timely interventions, improving MTBF and reducing downtime. Over time, these insights will evolve into prescriptive actions, including spares readiness, maintenance scheduling, and operating parameter adjustments, enabling reliability optimisation with minimal disruption.
A critical success factor is adoption. Predictive insights deliver value only when they are embedded into daily workflows, roles and accountability structures. Without this, they remain insights without action.
In a cost-sensitive market like India, how do cement companies balance digital investment with price competitiveness?
In India’s intensely competitive cement market, digital investments must be tightly linked to tangible business outcomes, particularly cost reduction, service improvement, and faster decision-making.
This balance is achieved by prioritising high-impact use cases such as planning efficiency, logistics optimisation, asset reliability, and process stability, all of which typically deliver quick payback. Equally important is building scalable and governed digital foundations that reduce the marginal cost of rolling out new use cases across plants.
Digitally enabled order management, live despatch visibility, and channel partner platforms also improve customer centricity while controlling cost-to-serve, allowing service levels to improve without proportionate increases in headcount or overheads.
In essence, the most effective digital investments do not add cost. They protect margins by reducing variability, improving planning accuracy, and strengthening execution discipline.
How is digitalisation enabling measurable reductions in energy consumption, emissions, and overall carbon footprint?
Digitalisation plays a pivotal role in improving energy efficiency, reducing emissions and lowering overall carbon intensity.
Real-time monitoring and analytics enable near real-time tracking of energy consumption and critical operating parameters, allowing inefficiencies to be identified quickly and corrective actions to be implemented. Centralised data consolidation across plants enables benchmarking, accelerates best-practice adoption, and drives consistent improvements in energy performance.
Improved asset reliability through predictive maintenance reduces unplanned downtime and process instability, directly lowering energy losses. Digital platforms also support more effective planning and control of renewable energy sources and waste heat recovery systems, reducing dependence on fossil fuels.
Most importantly, digitalisation enables sustainability progress to be tracked with greater accuracy and consistency, supporting long-term ESG commitments.
What role does digital supply chain visibility play in managing demand volatility and regional market dynamics in India?
Digital supply chain visibility is critical in India, where demand is highly regional, seasonality is pronounced, and logistics constraints can shift rapidly.
At Shree Cement, planning operates across multiple horizons. Annual planning focuses on capacity, network footprint and medium-term demand. Monthly S&OP aligns demand, production and logistics, while daily scheduling drives execution-level decisions on despatch, sourcing and prioritisation.
As digital maturity increases, this structure is being augmented by central command-and-control capabilities that manage exceptions such as plant constraints, demand spikes, route disruptions and order prioritisation. Planning is also shifting from aggregated averages to granular, cost-to-serve and exception-based decision-making, improving responsiveness, lowering logistics costs and strengthening service reliability.
How prepared is the current workforce for Industry 4.0, and what reskilling strategies are proving most effective?
Workforce preparedness for Industry 4.0 is improving, though the primary challenge lies in scaling capabilities consistently across diverse roles.
The most effective approach is to define capability requirements by role and tailor enablement accordingly. Senior leadership focuses on digital literacy for governance, investment prioritisation, and value tracking. Middle management is enabled to use analytics for execution discipline and adoption. Frontline sales and service teams benefit from
mobile-first tools and KPI-driven workflows, while shop-floor and plant teams focus on data-driven operations, APC usage, maintenance discipline, safety and quality routines.
Personalised, role-based learning paths, supported by on-ground champions and a clear articulation of practical benefits, drive adoption far more effectively than generic training programmes.
Which emerging digital technologies will fundamentally reshape cement manufacturing in the next decade?
AI and GenAI are expected to have the most significant impact, particularly when combined with connected operations and disciplined processes.
Key technologies likely to reshape the sector include GenAI and agentic AI for faster root-cause analysis, knowledge access, and standardisation of best practices; industrial foundation models that learn patterns across large sensor datasets; digital twins that allow simulation of process changes before implementation; and increasingly autonomous control systems that integrate sensors, AI, and APC to maintain stability with minimal manual intervention.
Over time, this will enable more centralised monitoring and management of plant operations, supported by strong processes, training and capability-building.
Concrete
Cement Additives for Improved Grinding Efficiency
Published
3 days agoon
February 20, 2026By
admin
Shreesh A Khadilkar discusses how advanced additive formulations allow customised, high-performance and niche cements—offering benefits while supporting blended cements and long-term cost and carbon reduction.
Cement additives are chemicals (inorganic and organic) added in small amounts (0.01 per cent to 0.2 per cent by weight) during cement grinding. Their main job? Reduce agglomeration, prevent pack-set, and keep the mill running smoother. Thus, these additions primarily improve, mill thru-puts, achieve lower clinker factor in blended cements PPC/PSC/PCC. Additionally, these additives improve concrete performance of cements or even for specific special premium cements with special USPs like lower setting times or for reduced water permeability in the resultant cement mortars and concrete (water repellent /permeation resistant cements), corrosion resistance etc.
The cement additives are materials which could be further differentiated as:
Grinding aids:
• Bottlenecks in cement grinding capacity, such materials can enhance throughputs
• Low specific electrical energy consumption during cement grinding
• Reduce “Pack set” problem and improve powder flowability
Quality improvers:
• Opportunity for further clinker factor reduction
• Solution for delayed cement setting or strength development issues at early or later ages.
Others: materials which are used for specific special cements with niche properties as discussed in the subsequent pages.
When cement additives are used as grinding aids or quality improvers, in general the additives reduce the inter-particle forces; reduce coating over grinding media and mill internals. Due to creation of like charges on cement particles, there is decreased agglomeration, much improved flowability, higher generation of fines better dispersion of particles in separator feed and reduction of mill filling level (decrease of residence time). However, in VRM grinding; actions need to be taken to have stable bed formation on the table.
It has been reported in literature and also substantiated by a number of detailed evaluations of different cement additive formulations in market, that the cement additive formulations are a combination of different chemical compounds, typically composed of:
- Accelerator/s for the hydration reaction of cements which are dependent on the acceleration effect desired in mortar compressive strengths at early or later ages, the choice of the materials is also dependent on clinker quality and blending components (flyash / slag) or a mix of both.
- Water reducer / workability / wet-ability enhancer, which would show impact on the resultant cement mortars and concrete. Some of the compounds (retarders) like polysaccharide derivatives, gluconates etc., show an initial retarding action towards hydration which result in reducing the water requirements for the cements thus act as water reducers, or it could be some appropriate polymeric molecules which show improved wet-ability and reduce water demand. These are selected based on the mineral component and type of cements (PPC/PSC /PCC).
- Grinding aids: Compounds that work as Grinding Aid i.e. which would enhance Mill thru-put on one hand as well as would increase the early strengths due to the higher fines generation/ or activation of cement components. These compounds could be like alkanol-amines such as TIPA, DEIPA, TEA etc. or could be compounds like glycols and other poly-ols, depending on whether it is OPC or PPC or PSC or PCC manufacture.
Mechanism of action — Step By Step—
- Reduce Agglomeration, Cement particles get electrostatically charged during grinding, stick together, form “flocs”, block mill efficiency, waste energy. Grinding aid molecules adsorb onto particle surfaces, neutralise charge, prevent re-agglomeration.
- Improve Powder Flowability, Adsorbed molecules create a lubricating layer, particles slide past each other easier, better mill throughput, less “dead zone” buildup.
Also reduces caking on mill liners, diaphragms, and separator screens, less downtime for cleaning. - Enhance Grinding Efficiency (Finer Product Faster), By preventing agglomeration, particles stay dispersed more surface area exposed to grinding media, finer grind achieved with same energy input, Or: same fineness achieved with less energy, huge savings.
Example:
• Without aid ? 3500 cm²/g Blaine needs 40 kWh/ton
• With use of optimum grinding aid same fineness at 32 kWh/ton 20 per cent energy savings - Reduce Pack Set and Silo Caking Grinding aids (GA) inhibit hydration of free lime (CaO) during storage prevents premature hardening or “pack set” in silos. especially critical in humid climates or with high free lime clinker.
It may be stated here that Overdosing of GA can cause: – Foaming in mill (especially with glycols) reduces grinding efficiency, retardation of cement setting (especially with amines/acids), odor issues (in indoor mills) – Corrosion of mill components (if acidic aids used improperly)
The best practice to optimise use of GA is Start with 0.02 per cent to 0.05 per cent dosage test fineness, flow, and set time adjust up/down. Due to static charge of particles, the sample may stick to the sides of sampler pipe and so sampling need to be properly done.
Depending on type of cements i.e. OPC, PPC, PSC, PCC, the grinding aids combinations need to be optimised, a typical Poly carboxylate ether also could be a part of the combo grinding aids
Cement additives for niche properties of the cement in concrete.
The cement additives can also be tailor made to create specific niche properties in cements, OPC, PPC, PSC and PCC to create premium or special brands. The special niche properties of the cement being its additional USP of such cement products, and are useful for customers to build a durable concrete structure with increased service life.
Such properties could be:
• Additives for improved concrete performance of cements, high early strength in PPC/PSC/PCC, much reduced water demand in cement, cements with improved slump retentivity in concrete, self-compacting, self levelling in concrete, cements with improved adhesion property of the cement mortar
• Water repellence / water proofing, permeability resistance in mortars and concrete.
• Biocidal cement
• Photo catalytic cements
• Cements with negligible ASR reactions etc.
Additives for cements for improved concrete performance
High early strengths: Use of accelerators. These are chemical compounds which enhance the degree of hydration of cement. These can include setting or hardening accelerators depending on whether their action occurs in the plastic or hardened state respectively. Thus, the setting accelerators reduce the setting time, whereas the hardening accelerators increase the early age strengths. The setting accelerators act during the initial minutes of the cement hydration, whereas the hardening accelerators act mainly during the initial days of hydration.
Chloride salts are the best in class. However, use of chloride salts as hardening accelerators are strongly discouraged for their action in promoting the corrosion of rebar, thus, chloride-free accelerators are preferred. The hardening accelerators could be combinations of compounds like nitrate, nitrite and thiocyanate salts of alkali or alkaline earth metals or thiosulphate, formate, and alkanol amines depending on the cement types.
However, especially in blended cements (PPC/PSC/PCC the increased early strengths invariably decrease the 28 day strengths. These aspects lead to creating combo additives along with organic polymers to achieve improved early strengths as well as either same or marginally improved 28 days strengths with reduced clinker factor in the blended cement, special OPC with reduced admixture requirements. With use of appropriate combination of inorganic and organic additives we could create an OPC with substantially reduced water demand or improved slump retentivity. Use of such an OPC would show exceptional concrete performance in high grade concretes as it would exhibit lower admixture requirements in High Grade Concretes.
PPC with OPC like properties: With the above concept we could have a PPC, having higher percentage flyash, with a combo cement additive which would have with concrete performance similar to OPC in say M40/M50 concrete. Such a PPC would produce a high-strength PPC concrete (= 60 MPa @ 28d) + improved workability, durability and sustainability.
Another interesting aspect could also be of using ultrafine fine flyash /ultrafine slags as additions in OPC/PPC/PSC for achieving lower clinker factor as well as to achieve improved later age strengths with or without a combo cement additive.
The initial adhesion property at sites of especially PPC/PSC/PCC based mortars can be improved through use of appropriate organic polymers addition during the manufacture of these cements. Such cements would have a better adhesion property for plastering/brick bonding etc., as it has much lower rebound loss of their mortars in such applications.
It is needless to mention here that with use of additives, we could also have cement with viscosity modifying cement additives, for self-compaction and self-leveling concrete performance.
Use of Phosphogypsum retards the setting time of cements, we can use additive different additive combos to overcome retardation and improve the 1 day strengths of the cements and concretes.
About the author:
Shreesh Khadilkar, Consultant & Advisor, Former Director Quality & Product Development, ACC, a seasoned consultant and advisor, brings over 37 years of experience in cement manufacturing, having held leadership roles in R&D and product development at ACC Ltd. With deep expertise in innovative cement concepts, he is dedicated to sharing his knowledge and improving the performance of cement plants globally.
Refractory demands in our kiln have changed
Digital supply chain visibility is critical
Redefining Efficiency with Digitalisation
Cement Additives for Improved Grinding Efficiency
Digital Pathways for Sustainable Manufacturing
Refractory demands in our kiln have changed
Digital supply chain visibility is critical
Redefining Efficiency with Digitalisation
Cement Additives for Improved Grinding Efficiency
Digital Pathways for Sustainable Manufacturing
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