Economy & Market
Maximising AFR in Cement Manufacturing
Published
1 year agoon
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admin
Shreesh A Khadilkar, Consultant and Advisor, and Former Director Quality and Product Development, ACC Ltd Thane, discusses the importance of optimising the use of alternative fuel and raw materials (TSR percentage) in cement production without affecting clinker quality, in part one of this two-part series.
Over the past decade or so, the Indian cement industry has made significant progress in terms of improvement in energy efficiency and productivity. However, the use of alternative fuel and raw material (AFR) to replace coal for thermal energy needs, remains an area where the Indian cement industry is yet to catch up with global benchmarks. Though a few cement plants co-process large quantities and varieties of AFR in their kilns, and are reported to reach a level of around 40 per cent Thermal Substitution Rate (TSR), many plants are still at much lower levels of TSR percentage.
Most of the cement plants have now installed co-processing facilities or are on the verge of having one. Some of the plants also have pre-processing facilities, which could include shredding, segregation, impregnation, foreign body removal etc., while some others source a pre-processed solid AFR (RDF, MSW, Industrial waste sludges, agro wastes etc.).
This article shares important aspects such as assessment of clinker quality in plant clinker quality optimisation, influence of alkalis, chlorides and SO3, effects of some important minor constituents and subsequently discusses the concept for maximising AFR (TSR percentage) without affecting clinker quality through with or without use of XRD technique for in process control. The author further recommends bi-hourly quality and in process dashboard for consistent kiln performance and consistent clinker quality.
Assessment of Clinker Quality
The clinker quality assessment can best be done by Lab Ball Mill grinding of day average clinker with mineral gypsum (with SO3 of the lab ground cement targeted at 2.2 to 2.4 with fixed grinding time to achieve Blaine’s of around 300-320 M2/kg with the residue on 45 microns of the cement in range of 18 per cent to 20 per cent, at this fineness, the clinker is observed to clearly depict changes in clinker reactivity in terms of changes in 1 Day strengths of cements (± 3 to 5 MPa). At lower grinding Blaine’s (of around 250 M2/kg), which is presently being practiced by many cement plants, one does not observe the changes in clinker reactivity, as the difference of 1 Day compressive strengths is only ± 1 MPa, which does not show the changes in clinker reactivity.
Typically, clinkers with good reactivity are observed to show 1 Day strengths in lab ground cements of 30 to 35 MPa. Higher values being observed when clinker alkali sulphates are high (especially with Petcoke as fuel), the achieved Blaine’s and quantity of nibs removed from the lab ground cement, in the fixed grinding time is also indicative of clinker grindability. Judicious raw mix optimisation with existing or alternative corrective materials (with the fuel mix used by the plant) can be attempted so as to have a clinker with improved reactivity/hydraulic potential. In a running plant the approach has to be by attempting small gradual changes to clinker composition and assessing the impact of the changes, on kiln performance and clinker quantity.
The changes to be attempted could be indicated through data analysis.
In each plant, the QC and process has detailed analysis data of the day average clinkers along with its lab ground cement test results. It is also suggested to test at least one spot clinker per day for chemical parameters and physical tests of lab ground cement. From the analysis data it could be observed that on some days the lab ground cements show much higher strengths. Why on some days or in some spot clinkers, the clinker reactivity is suddenly very good? Such clinkers should be preserved and evaluated by XRD, so as to identify the optimum clinker composition which shows higher reactivity. Such an evaluation could also indicate at times the impact of changes in fuel / sources of coal / proportions of coal and Petcoke (even source of Petcoke) / solid AFR usage levels.
Typically, the target clinker composition to give a good hydraulic potential would be with LSF of 93 to 95 with a bogues potential C3S of >55 per cent clinker (especially with Petcoke as main fuel in fuel mix), with C3A (6.5 per cent to 8.5 per cent) if the clinker is used for PPC/PSC and also for OPC (especially if OPC is supplied to RMX customers) and SM 2.2 to 2.4 A/F 1.2 to 1.4. In plants where clinker MgO is higher (> 4.5 per cent), besides having the LSF target of around 93 to 95, the minimum clinker lime targeted should be such to have C/S ratio of 2.95 to 3.1 for having good clinker reactivity in spite of high clinker MgO.

Co-Processing of AFR (Liquid AFR /Solid AFR)
The properties of AF(R) co-processed in the calciner have an impact on environment, health and safety, plant operations and product quality as shown in Table 1:
- Alkalis without sulphidisation: Formation of orthorhombic C3A, fast setting
- Alkali sulphates (Na2SO4, K2SO4, 2CaSO4.K2SO4 or even Ca-langebnite): Increased early strength, usually shows decrease of later age strengths. Changes must be accounted for in gypsum optimisation
- Excess of sulphur over alkalis
- Integration of SO3 in C2S and/or formation of CaSO4
- Possible reduction of final strength could be observed
- Reduces the CaO availability for C3S formation
- The clinker could be harder to grand
- Changes the Clinker Liquid Characteristics which affects the phase formations
- Chlorides tend to be higher in AFR liquid/solid, the control on chlorides is necessary to prevent inlet/cyclone jamming and to have < 0.06 per cent in clinker, so that the OPC has <0.04 per cent chlorides and is suitable for
- RMC/structural concrete. To avoid problems of kiln inlet and cyclone jamming caused by SO3 and Cl. Preferably maintain the Hot Meal (2 Cl + SO3) < 3.5. The threshold value for a given plant needs to
be assessed.
If the value goes above the plant threshold value, immediate actions of adding caustic soda for 2 to 3 shifts (in small polyethene bags) should be done to remove the depositions and avoid kiln stoppage.
Effects of some minor constituents on the clinker quality
Effects of ZnO
- Zinc in clinker nearly distributes evenly between the silicates ad matrix phases (with preference to ferrite), trigonal C3S and ß C2S is stabilised by zinc.
- Presence of zinc reduces the amount of aluminates in favour of alumino ferrite.
- Each 1 per cent zinc reduces aluminates by
1 per cent and increases alumino-ferrites by
2 per cent. - Zinc is very effective flux and mineraliser, it lowers clinkerisation temperatures and accelerates lime combination. Knofel reports increased comp. strengths by up to 20 per cent and above at early ages.
Effects of TiO2
- The clinker TiO2 should be <0.7 per cent, it should be noted that TiO2 is a viscous flux like Al2O3 and so for understanding the clinker liquid property for good C3S formation and based on the kiln conditions adjust the clinker Fe2O3 contents accordingly.
- At higher TiO2, contents for improved kiln conditions the clinker Fe2O3 content needs to be much higher which is aggravated if clinker SO3 is higher (which also affects the viscosity of clinker liquid)
- At high total liquid the clinker becomes silica deficient and so free lime tends to be higher (with clinker balls with calcined un sintered material inside)
- In plants that use red mud especially with petcoke due to its higher alkalis, many sources of red muds also have TiO2, the plant should target Al2O3 + TiO2 as the viscous flux and then adjust the clinker Fe2O3 to get good kiln conditions as indicated above. Targeting higher liquid only increases the limestone LSF from mines and also affects clinker grindability.
Effects P2O5 sources
- Many types of agriculture waste, biowastes, phosphate sludge, paint sludges, medical waste, RDF/municipal solid waste, expired detergent, cow dung cakes, etc.
- Under Indian conditions of clinker phase composition, any increase of P2O5 contents can substantially affect clinker quality.
- When higher P2O5 are present, the dicalcium silicate (C2S) is stabilised and inhibits formation of alite (C3S) i.e can decrease the percentage of C3S although bogue may show high percentage C3S.
- When P2O5 present exceeds 0.4 per cent in the clinker it reduces the percentage of C3S by 10 per cent and 1 Day Comp. Strengths by around 5-6 MPa with negative effects on clinker reactivity and setting of cement.
- Use of wastes containing phosphates in controlled manner so that P2O5 in the clinker (maximum limit in clinker is 0.25 per cent) can enhance the use of agricultural waste or use of other wastes with P2O5. It may be noted that in some regions limestone and laterite also have shown P2O5 contents.
- In some plants up to 5 to 7 per cent TSR there is no impact observed on quality or productivity, however as the TSR/AFR percentage is increased say above >8 per cent to 10 per cent, the kiln conditions get frequently disturbed with a very high dust generation and there is a drop in clinker reactivity/quality.
In the plants a judicious study of process conditions and understanding the burnability of kiln feed could help achieve productivity without affecting the clinker quality with increased AFR/TSR.
In one of my consultancy visits to an integrated plant, similar observations as above were reported. In a brainstorming discussions with the plant process, production and QC teams, it was noted that:
- There was substantial variation in calciner outlet/kiln inlet material/C6 material temperature it fluctuated from around 920oC to as low as 860oC, these changes in temperatures nearly corresponded with the fluctuation in percentage of moisture and feed rate of solid AFR (SAFR), RDF and other solid wastes.
- The kiln torque decreased below the desired levels, when the calciner outlet and kiln inlet material temperatures (in this case C6 material temperatures) were less than 890oC and the kiln performance showed high dust recirculation/generation.
- The bi-hourly XRF analysis of clinker showed lower LSF/high free lime. The decrease in clinker LSF was understandable as the SAFR ash showed a higher percentage of ash.
It was decided to collect hot meal samples 900oC to 910oC and 920oC to 930oC and also corresponding clinker samples collected after 40 minutes of the sample collection time of hot meal samples. The hot meal samples were analysed for XRD and clinker samples for XRF (Chemical analysis with free lime) and XRD (for clinker phase formation).
The XRD analysis of hot meal samples is shown in Table 2.
The XRD analysis indicates that:
- The calcination percentage is much higher than the convention DOC of hot meal samples.
- The un-combined CaO decreases with increase in temperature of collected sample.
- The total belite increases with increase in temperature.
It was observed in the plant that when attempts were made to maintain the kiln inlet material temperature at 910oC to 920oC, the kiln torque showed an improvement and the kiln performance improved. The clinker quality showed improvements with lower free lime. However due to the fluctuations in ash percentage content of SAFR the clinker LSF showed lower values during the day. As a corrective action, lime sludge (available at the plant) was added on the SAFR conveyor. These corrective actions helped achieve a consistent improved clinker quality.
About the author:
With an MSc in Organic Chemistry from Jodhpur University (now JNV University), Shreesh Khadilkar joined ACC’s Organic Chemical Product Development Division in 1981 and later transitioned to the Cement R&D Division as a technical assistant. He took over as VP of R&D (Quality and Product Development Division) and retired as Director of the department in 2018, with over 37 years of experience in cement manufacturing and cements/cementitious products.


Concrete
Refractory demands in our kiln have changed
Published
3 days agoon
February 20, 2026By
admin
Radha Singh, Senior Manager (P&Q), Shree Digvijay Cement, points out why performance, predictability and life-cycle value now matter more than routine replacement in cement kilns.
As Indian cement plants push for higher throughput, increased alternative fuel usage and tighter shutdown cycles, refractory performance in kilns and pyro-processing systems is under growing pressure. In this interview, Radha Singh, Senior Manager (P&Q), Shree Digvijay Cement, shares how refractory demands have evolved on the ground and how smarter digital monitoring is improving kiln stability, uptime and clinker quality.
How have refractory demands changed in your kiln and pyro-processing line over the last five years?
Over the last five years, refractory demands in our kiln and pyro line have changed. Earlier, the focus was mostly on standard grades and routine shutdown-based replacement. But now, because of higher production loads, more alternative fuels and raw materials (AFR) usage and greater temperature variation, the expectation from refractory has increased.
In our own case, the current kiln refractory has already completed around 1.5 years, which itself shows how much more we now rely on materials that can handle thermal shock, alkali attack and coating fluctuations. We have moved towards more stable, high-performance linings so that we don’t have to enter the kiln frequently for repairs.
Overall, the shift has been from just ‘installation and run’ to selecting refractories that give longer life, better coating behaviour and more predictable performance under tougher operating conditions.
What are the biggest refractory challenges in the preheater, calciner and cooler zones?
• Preheater: Coating instability, chloride/sulphur cycles and brick erosion.
• Calciner: AFR firing, thermal shock and alkali infiltration.
• Cooler: Severe abrasion, red-river formation and mechanical stress on linings.
Overall, the biggest challenge is maintaining lining stability under highly variable operating conditions.
How do you evaluate and select refractory partners for long-term performance?
In real plant conditions, we don’t select a refractory partner just by looking at price. First, we see their past performance in similar kilns and whether their material has actually survived our operating conditions. We also check how strong their technical support is during shutdowns, because installation quality matters as much as the material itself.
Another key point is how quickly they respond during breakdowns or hot spots. A good partner should be available on short notice. We also look at their failure analysis capability, whether they can explain why a lining failed and suggest improvements.
On top of this, we review the life they delivered in the last few campaigns, their supply reliability and their willingness to offer plant-specific custom solutions instead of generic grades. Only a partner who supports us throughout the life cycle, which includes selection, installation, monitoring and post-failure analysis, fits our long-term requirement.
Can you share a recent example where better refractory selection improved uptime or clinker quality?
Recently, we upgraded to a high-abrasion basic brick at the kiln outlet. Earlier we had frequent chipping and coating loss. With the new lining, thermal stability improved and the coating became much more stable. As a result, our shutdown interval increased and clinker quality remained more consistent. It had a direct impact on our uptime.
How is increased AFR use affecting refractory behaviour?
Increased AFR use is definitely putting more stress on the refractory. The biggest issue we see daily is the rise in chlorine, alkalis and volatiles, which directly attack the lining, especially in the calciner and kiln inlet. AFR firing is also not as stable as conventional fuel, so we face frequent temperature fluctuations, which cause more thermal shock and small cracks in the lining.
Another real problem is coating instability. Some days the coating builds too fast, other days it suddenly drops, and both conditions impact refractory life. We also notice more dust circulation and buildup inside the calciner whenever the AFR mix changes, which again increases erosion.
Because of these practical issues, we have started relying more on alkali-resistant, low-porosity and better thermal shock–resistant materials to handle the additional stress coming from AFR.
What role does digital monitoring or thermal profiling play in your refractory strategy?
Digital tools like kiln shell scanners, IR imaging and thermal profiling help us detect weakening areas much earlier. This reduces unplanned shutdowns, helps identify hotspots accurately and allows us to replace only the critical sections. Overall, our maintenance has shifted from reactive to predictive, improving lining life significantly.
How do you balance cost, durability and installation speed during refractory shutdowns?
We focus on three points:
• Material quality that suits our thermal profile and chemistry.
• Installation speed, in fast turnarounds, we prefer monolithic.
• Life-cycle cost—the cheapest material is not the most economical. We look at durability, future downtime and total cost of ownership.
This balance ensures reliable performance without unnecessary expenditure.
What refractory or pyro-processing innovations could transform Indian cement operations?
Some promising developments include:
• High-performance, low-porosity and nano-bonded refractories
• Precast modular linings to drastically reduce shutdown time
• AI-driven kiln thermal analytics
• Advanced coating management solutions
• More AFR-compatible refractory mixes
These innovations can significantly improve kiln stability, efficiency and maintenance planning across the industry.
Concrete
Digital supply chain visibility is critical
Published
3 days agoon
February 20, 2026By
admin
MSR Kali Prasad, Chief Digital and Information Officer, Shree Cement, discusses how data, discipline and scale are turning Industry 4.0 into everyday business reality.
Over the past five years, digitalisation in Indian cement manufacturing has moved decisively beyond experimentation. Today, it is a strategic lever for cost control, operational resilience and sustainability. In this interview, MSR Kali Prasad, Chief Digital and Information Officer, Shree Cement, explains how integrated digital foundations, advanced analytics and real-time visibility are helping deliver measurable business outcomes.
How has digitalisation moved from pilot projects to core strategy in Indian cement manufacturing over the past five years?
Digitalisation in Indian cement has evolved from isolated pilot initiatives into a core business strategy because outcomes are now measurable, repeatable and scalable. The key shift has been the move away from standalone solutions toward an integrated digital foundation built on standardised processes, governed data and enterprise platforms that can be deployed consistently across plants and functions.
At Shree Cement, this transition has been very pragmatic. The early phase focused on visibility through dashboards, reporting, and digitisation of critical workflows. Over time, this has progressed into enterprise-level analytics and decision support across manufacturing and the supply chain,
with clear outcomes in cost optimisation, margin protection and revenue improvement through enhanced customer experience.
Equally important, digital is no longer the responsibility of a single function. It is embedded into day-to-day operations across planning, production, maintenance, despatch and customer servicing, supported by enterprise systems, Industrial Internet of Things (IIoT) data platforms, and a structured approach to change management.
Which digital interventions are delivering the highest ROI across mining, production and logistics today?
In a capital- and cost-intensive sector like cement, the highest returns come from digital interventions that directly reduce unit costs or unlock latent capacity without significant capex.
Supply chain and planning (advanced analytics): Tools for demand forecasting, S&OP, network optimisation and scheduling deliver strong returns by lowering logistics costs, improving service levels, and aligning production with demand in a fragmented and regionally diverse market.
Mining (fleet and productivity analytics): Data-led mine planning, fleet analytics, despatch discipline, and idle-time reduction improve fuel efficiency and equipment utilisation, generating meaningful savings in a cost-heavy operation.
Manufacturing (APC and process analytics): Advanced Process Control, mill optimisation, and variability reduction improve thermal and electrical efficiency, stabilise quality and reduce rework and unplanned stoppages.
Customer experience and revenue enablement (digital platforms): Dealer and retailer apps, order visibility and digitally enabled technical services improve ease of doing business and responsiveness. We are also empowering channel partners with transparent, real-time information on schemes, including eligibility, utilisation status and actionable recommendations, which improves channel satisfaction and market execution while supporting revenue growth.
Overall, while Artificial Intelligence (AI) and IIoT are powerful enablers, it is advanced analytics anchored in strong processes that typically delivers the fastest and most reliable ROI.
How is real-time data helping plants shift from reactive maintenance to predictive and prescriptive operations?
Real-time and near real-time data is driving a more proactive and disciplined maintenance culture, beginning with visibility and progressively moving toward prediction and prescription.
At Shree Cement, we have implemented a robust SAP Plant Maintenance framework to standardise maintenance workflows. This is complemented by IIoT-driven condition monitoring, ensuring consistent capture of equipment health indicators such as vibration, temperature, load, operating patterns and alarms.
Real-time visibility enables early detection of abnormal conditions, allowing teams to intervene before failures occur. As data quality improves and failure histories become structured, predictive models can anticipate likely failure modes and recommend timely interventions, improving MTBF and reducing downtime. Over time, these insights will evolve into prescriptive actions, including spares readiness, maintenance scheduling, and operating parameter adjustments, enabling reliability optimisation with minimal disruption.
A critical success factor is adoption. Predictive insights deliver value only when they are embedded into daily workflows, roles and accountability structures. Without this, they remain insights without action.
In a cost-sensitive market like India, how do cement companies balance digital investment with price competitiveness?
In India’s intensely competitive cement market, digital investments must be tightly linked to tangible business outcomes, particularly cost reduction, service improvement, and faster decision-making.
This balance is achieved by prioritising high-impact use cases such as planning efficiency, logistics optimisation, asset reliability, and process stability, all of which typically deliver quick payback. Equally important is building scalable and governed digital foundations that reduce the marginal cost of rolling out new use cases across plants.
Digitally enabled order management, live despatch visibility, and channel partner platforms also improve customer centricity while controlling cost-to-serve, allowing service levels to improve without proportionate increases in headcount or overheads.
In essence, the most effective digital investments do not add cost. They protect margins by reducing variability, improving planning accuracy, and strengthening execution discipline.
How is digitalisation enabling measurable reductions in energy consumption, emissions, and overall carbon footprint?
Digitalisation plays a pivotal role in improving energy efficiency, reducing emissions and lowering overall carbon intensity.
Real-time monitoring and analytics enable near real-time tracking of energy consumption and critical operating parameters, allowing inefficiencies to be identified quickly and corrective actions to be implemented. Centralised data consolidation across plants enables benchmarking, accelerates best-practice adoption, and drives consistent improvements in energy performance.
Improved asset reliability through predictive maintenance reduces unplanned downtime and process instability, directly lowering energy losses. Digital platforms also support more effective planning and control of renewable energy sources and waste heat recovery systems, reducing dependence on fossil fuels.
Most importantly, digitalisation enables sustainability progress to be tracked with greater accuracy and consistency, supporting long-term ESG commitments.
What role does digital supply chain visibility play in managing demand volatility and regional market dynamics in India?
Digital supply chain visibility is critical in India, where demand is highly regional, seasonality is pronounced, and logistics constraints can shift rapidly.
At Shree Cement, planning operates across multiple horizons. Annual planning focuses on capacity, network footprint and medium-term demand. Monthly S&OP aligns demand, production and logistics, while daily scheduling drives execution-level decisions on despatch, sourcing and prioritisation.
As digital maturity increases, this structure is being augmented by central command-and-control capabilities that manage exceptions such as plant constraints, demand spikes, route disruptions and order prioritisation. Planning is also shifting from aggregated averages to granular, cost-to-serve and exception-based decision-making, improving responsiveness, lowering logistics costs and strengthening service reliability.
How prepared is the current workforce for Industry 4.0, and what reskilling strategies are proving most effective?
Workforce preparedness for Industry 4.0 is improving, though the primary challenge lies in scaling capabilities consistently across diverse roles.
The most effective approach is to define capability requirements by role and tailor enablement accordingly. Senior leadership focuses on digital literacy for governance, investment prioritisation, and value tracking. Middle management is enabled to use analytics for execution discipline and adoption. Frontline sales and service teams benefit from
mobile-first tools and KPI-driven workflows, while shop-floor and plant teams focus on data-driven operations, APC usage, maintenance discipline, safety and quality routines.
Personalised, role-based learning paths, supported by on-ground champions and a clear articulation of practical benefits, drive adoption far more effectively than generic training programmes.
Which emerging digital technologies will fundamentally reshape cement manufacturing in the next decade?
AI and GenAI are expected to have the most significant impact, particularly when combined with connected operations and disciplined processes.
Key technologies likely to reshape the sector include GenAI and agentic AI for faster root-cause analysis, knowledge access, and standardisation of best practices; industrial foundation models that learn patterns across large sensor datasets; digital twins that allow simulation of process changes before implementation; and increasingly autonomous control systems that integrate sensors, AI, and APC to maintain stability with minimal manual intervention.
Over time, this will enable more centralised monitoring and management of plant operations, supported by strong processes, training and capability-building.
Concrete
Cement Additives for Improved Grinding Efficiency
Published
3 days agoon
February 20, 2026By
admin
Shreesh A Khadilkar discusses how advanced additive formulations allow customised, high-performance and niche cements—offering benefits while supporting blended cements and long-term cost and carbon reduction.
Cement additives are chemicals (inorganic and organic) added in small amounts (0.01 per cent to 0.2 per cent by weight) during cement grinding. Their main job? Reduce agglomeration, prevent pack-set, and keep the mill running smoother. Thus, these additions primarily improve, mill thru-puts, achieve lower clinker factor in blended cements PPC/PSC/PCC. Additionally, these additives improve concrete performance of cements or even for specific special premium cements with special USPs like lower setting times or for reduced water permeability in the resultant cement mortars and concrete (water repellent /permeation resistant cements), corrosion resistance etc.
The cement additives are materials which could be further differentiated as:
Grinding aids:
• Bottlenecks in cement grinding capacity, such materials can enhance throughputs
• Low specific electrical energy consumption during cement grinding
• Reduce “Pack set” problem and improve powder flowability
Quality improvers:
• Opportunity for further clinker factor reduction
• Solution for delayed cement setting or strength development issues at early or later ages.
Others: materials which are used for specific special cements with niche properties as discussed in the subsequent pages.
When cement additives are used as grinding aids or quality improvers, in general the additives reduce the inter-particle forces; reduce coating over grinding media and mill internals. Due to creation of like charges on cement particles, there is decreased agglomeration, much improved flowability, higher generation of fines better dispersion of particles in separator feed and reduction of mill filling level (decrease of residence time). However, in VRM grinding; actions need to be taken to have stable bed formation on the table.
It has been reported in literature and also substantiated by a number of detailed evaluations of different cement additive formulations in market, that the cement additive formulations are a combination of different chemical compounds, typically composed of:
- Accelerator/s for the hydration reaction of cements which are dependent on the acceleration effect desired in mortar compressive strengths at early or later ages, the choice of the materials is also dependent on clinker quality and blending components (flyash / slag) or a mix of both.
- Water reducer / workability / wet-ability enhancer, which would show impact on the resultant cement mortars and concrete. Some of the compounds (retarders) like polysaccharide derivatives, gluconates etc., show an initial retarding action towards hydration which result in reducing the water requirements for the cements thus act as water reducers, or it could be some appropriate polymeric molecules which show improved wet-ability and reduce water demand. These are selected based on the mineral component and type of cements (PPC/PSC /PCC).
- Grinding aids: Compounds that work as Grinding Aid i.e. which would enhance Mill thru-put on one hand as well as would increase the early strengths due to the higher fines generation/ or activation of cement components. These compounds could be like alkanol-amines such as TIPA, DEIPA, TEA etc. or could be compounds like glycols and other poly-ols, depending on whether it is OPC or PPC or PSC or PCC manufacture.
Mechanism of action — Step By Step—
- Reduce Agglomeration, Cement particles get electrostatically charged during grinding, stick together, form “flocs”, block mill efficiency, waste energy. Grinding aid molecules adsorb onto particle surfaces, neutralise charge, prevent re-agglomeration.
- Improve Powder Flowability, Adsorbed molecules create a lubricating layer, particles slide past each other easier, better mill throughput, less “dead zone” buildup.
Also reduces caking on mill liners, diaphragms, and separator screens, less downtime for cleaning. - Enhance Grinding Efficiency (Finer Product Faster), By preventing agglomeration, particles stay dispersed more surface area exposed to grinding media, finer grind achieved with same energy input, Or: same fineness achieved with less energy, huge savings.
Example:
• Without aid ? 3500 cm²/g Blaine needs 40 kWh/ton
• With use of optimum grinding aid same fineness at 32 kWh/ton 20 per cent energy savings - Reduce Pack Set and Silo Caking Grinding aids (GA) inhibit hydration of free lime (CaO) during storage prevents premature hardening or “pack set” in silos. especially critical in humid climates or with high free lime clinker.
It may be stated here that Overdosing of GA can cause: – Foaming in mill (especially with glycols) reduces grinding efficiency, retardation of cement setting (especially with amines/acids), odor issues (in indoor mills) – Corrosion of mill components (if acidic aids used improperly)
The best practice to optimise use of GA is Start with 0.02 per cent to 0.05 per cent dosage test fineness, flow, and set time adjust up/down. Due to static charge of particles, the sample may stick to the sides of sampler pipe and so sampling need to be properly done.
Depending on type of cements i.e. OPC, PPC, PSC, PCC, the grinding aids combinations need to be optimised, a typical Poly carboxylate ether also could be a part of the combo grinding aids
Cement additives for niche properties of the cement in concrete.
The cement additives can also be tailor made to create specific niche properties in cements, OPC, PPC, PSC and PCC to create premium or special brands. The special niche properties of the cement being its additional USP of such cement products, and are useful for customers to build a durable concrete structure with increased service life.
Such properties could be:
• Additives for improved concrete performance of cements, high early strength in PPC/PSC/PCC, much reduced water demand in cement, cements with improved slump retentivity in concrete, self-compacting, self levelling in concrete, cements with improved adhesion property of the cement mortar
• Water repellence / water proofing, permeability resistance in mortars and concrete.
• Biocidal cement
• Photo catalytic cements
• Cements with negligible ASR reactions etc.
Additives for cements for improved concrete performance
High early strengths: Use of accelerators. These are chemical compounds which enhance the degree of hydration of cement. These can include setting or hardening accelerators depending on whether their action occurs in the plastic or hardened state respectively. Thus, the setting accelerators reduce the setting time, whereas the hardening accelerators increase the early age strengths. The setting accelerators act during the initial minutes of the cement hydration, whereas the hardening accelerators act mainly during the initial days of hydration.
Chloride salts are the best in class. However, use of chloride salts as hardening accelerators are strongly discouraged for their action in promoting the corrosion of rebar, thus, chloride-free accelerators are preferred. The hardening accelerators could be combinations of compounds like nitrate, nitrite and thiocyanate salts of alkali or alkaline earth metals or thiosulphate, formate, and alkanol amines depending on the cement types.
However, especially in blended cements (PPC/PSC/PCC the increased early strengths invariably decrease the 28 day strengths. These aspects lead to creating combo additives along with organic polymers to achieve improved early strengths as well as either same or marginally improved 28 days strengths with reduced clinker factor in the blended cement, special OPC with reduced admixture requirements. With use of appropriate combination of inorganic and organic additives we could create an OPC with substantially reduced water demand or improved slump retentivity. Use of such an OPC would show exceptional concrete performance in high grade concretes as it would exhibit lower admixture requirements in High Grade Concretes.
PPC with OPC like properties: With the above concept we could have a PPC, having higher percentage flyash, with a combo cement additive which would have with concrete performance similar to OPC in say M40/M50 concrete. Such a PPC would produce a high-strength PPC concrete (= 60 MPa @ 28d) + improved workability, durability and sustainability.
Another interesting aspect could also be of using ultrafine fine flyash /ultrafine slags as additions in OPC/PPC/PSC for achieving lower clinker factor as well as to achieve improved later age strengths with or without a combo cement additive.
The initial adhesion property at sites of especially PPC/PSC/PCC based mortars can be improved through use of appropriate organic polymers addition during the manufacture of these cements. Such cements would have a better adhesion property for plastering/brick bonding etc., as it has much lower rebound loss of their mortars in such applications.
It is needless to mention here that with use of additives, we could also have cement with viscosity modifying cement additives, for self-compaction and self-leveling concrete performance.
Use of Phosphogypsum retards the setting time of cements, we can use additive different additive combos to overcome retardation and improve the 1 day strengths of the cements and concretes.
About the author:
Shreesh Khadilkar, Consultant & Advisor, Former Director Quality & Product Development, ACC, a seasoned consultant and advisor, brings over 37 years of experience in cement manufacturing, having held leadership roles in R&D and product development at ACC Ltd. With deep expertise in innovative cement concepts, he is dedicated to sharing his knowledge and improving the performance of cement plants globally.
Refractory demands in our kiln have changed
Digital supply chain visibility is critical
Redefining Efficiency with Digitalisation
Cement Additives for Improved Grinding Efficiency
Digital Pathways for Sustainable Manufacturing
Refractory demands in our kiln have changed
Digital supply chain visibility is critical
Redefining Efficiency with Digitalisation
Cement Additives for Improved Grinding Efficiency
Digital Pathways for Sustainable Manufacturing
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Concrete4 weeks agoAris Secures Rs 630 Million Concrete Supply Order
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Concrete4 weeks agoNITI Aayog Unveils Decarbonisation Roadmaps
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Concrete3 weeks agoJK Cement Commissions 3 MTPA Buxar Plant, Crosses 31 MTPA
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Economy & Market3 weeks agoBudget 2026–27 infra thrust and CCUS outlay to lift cement sector outlook


