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Green Hydrogen

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Dr SB Hegde, Professor, Department of Civil Engineering, Jain College of Engineering and Technology, discusses how green hydrogen is a game changer for carbon-neutral cement production in India.

India’s cement industry produces nearly 7 per cent of global CO2 emissions and must move toward Net Zero by 2070. Green hydrogen, made from renewable energy, is a game changer that can replace fossil fuels in cement kilns, helping to cut emissions, modernise cement production, and achieve carbon neutrality.
This paper explores green hydrogen’s potential, early adoption in India, technical and safety requirements and the role of supportive policies. Using global and Indian examples, it presents a phased roadmap with clear data to guide the industry toward a sustainable, carbon-neutral future.

Introduction
India’s cement industry produces more than 350 million tonnes of cement each year and is expected to reach about 451 million tonnes by FY27. While it is one of the largest in the world, it also adds nearly 7 per cent of global CO2 emissions. Around 32 per cent of these emissions come from burning fuels, and 56 per cent come from the chemical process of calcination (IBEF, 2025; IEA, 2020).
To achieve India’s goal of Net Zero emissions by 2070, cleaner alternatives are needed. Green hydrogen—produced using renewable energy through electrolysis—can be a game changer by replacing coal and pet coke in cement kilns. Just like shifting from a smoky coal stove to a clean electric one, green hydrogen supports the ‘3Cs’: Cut emissions, bring innovation to Cement, and move toward Carbon neutrality.
This paper discusses the potential of green hydrogen in cement production, its current status, challenges, technical requirements, government policies and a step-by-step roadmap. By sharing success stories from India and abroad, including companies like Ambuja and Dalmia, it aims to encourage the industry to lead the green transition.

The promise of green hydrogen
Green hydrogen can transform cement production by eliminating the 32 per cent of emissions from burning coal in kilns, cutting ~0.32 million tonnes of CO2 annually for a one million tonne per annum (MTPA) plant (IEA, 2020).
Combined with alternatives like fly ash for clinker and carbon capture, it could reduce emissions by 66–95 per cent by 2050. Unlike biomass, which some plants use to cut emissions by 10 per cent but struggle with unreliable supply (UltraTech, 2024), hydrogen burns consistently at 1400–1500°C, like a steady flame in a gas stove. India’s National Green Hydrogen Mission (NGHM), targeting 125 GW of renewable energy by 2030, supports this shift (MNRE, 2023). Figure 1 shows the potential CO2 reductions.

Current status
The use of green hydrogen in India’s cement industry is still at a very early stage, with less than 5 per cent of plants experimenting with it (CSTEP, 2025). Some key pilots include:

  • Adani Cement (Mundra): Ambuja Cements has started a Rs.830 crore project using solar-powered hydrogen, which has helped reduce emissions by about 10 per cent (Devdiscourse, 2025).
  • Chhattisgarh Pilot: A smaller plant is testing hydrogen by burning 325 kg per year for calcination. This setup, costing Rs.10 crore, has cut emissions by 5 per cent (IGI Global, 2025).

These projects are like the first sparks of a larger fire—showing that hydrogen works—but scaling it up across the industry will require solving major challenges.

Critical challenges
Using green hydrogen in cement plants is promising, but there are several big challenges that need solutions:

  • Limited scale: Because of high costs and low awareness, only a few plants are testing hydrogen.
    Infrastructure gaps: As of 2025, India has only three hydrogen refueling stations—like having just a few petrol pumps for an entire city (TERI, 2024).
  • High costs: Hydrogen currently costs Rs.300–500 per kg, while coal costs only Rs.6,000–8,000 per tonne (about Rs.30,000 per tonne in energy terms). On top of that, each plant would need electrolysers costing Rs.50–70 crore.
  • Technical skills: Converting kilns to use hydrogen requires new expertise, similar to learning to cook with a new type of fuel. Training and retrofitting can cost Rs.5–10 crore per plant.
  • Energy demand: Producing one kg of hydrogen needs about 50 kWh of electricity, so large solar or wind farms are required to avoid putting extra pressure on the power grid.

These barriers are serious, but as the next section explains, strong government policies can play a key role in overcoming them.

Government support and policy framework
The Indian government is actively supporting the use of green hydrogen in cement production through several key policies:

  • National Green Hydrogen Mission (NGHM): A budget of Rs.19,744 crore has been set aside, with Rs.17,490 crore for production incentives and Rs.1,466 crore for pilot projects in sectors like cement (MNRE, 2023). The scheme covers up to 50 per cent of electrolyser costs (up to Rs.25 crore per plant) and waives interstate renewable energy transmission charges until 2030—like getting a discount on new equipment plus free delivery.
  • Carbon Credit Trading Scheme (CCTS): Under the amended Energy Conservation Act (2001, 2022), plants can earn Rs.2,000 for every tonne of CO2 they reduce, similar to collecting reward points for eco-friendly actions.
    CPCB regulations: The Central Pollution Control Board has set strict emission limits (for example, 30 mg/Nm³ for dust). Using hydrogen lowers dust and NOx, making it easier for plants to meet the 2025 standards (CPCB, 2025).
  • Safety Standards: The Petroleum and Explosives Safety Organisation (PESO) require plants to use leak-proof storage tanks and train workers properly, much like safety rules for handling a gas stove (PESO, 2025).
  • Infrastructure Support: Around Rs.4,500 crore is being invested to build refuelling stations and pipelines by 2030, which will make distribution smoother.

Together, these policies make it easier and more practical for cement companies to adopt hydrogen, as already seen in both Indian and global pilot projects.

Success stories: Global and Indian pioneers
Examples from around the world and India show how green hydrogen can work in cement production:

  • Heidelberg Materials (Germany): Installed a Rs.370 crore, 30 MW electrolyser at Hannover that replaced 20 per cent of coal use, cutting emissions by 25 per cent (H2 Bulletin, 2024).
  • Cemex (Spain): Used hydrogen injection at its Alicante plant to reduce coal use by 15 per cent, cutting 10,000 tonnes of CO2 each year with very little modification needed (Cemex, 2020).
  • Adani Cement (India): At Mundra, a pilot project shows how green hydrogen can be scaled up using renewable energy (Devdiscourse, 2025).
  • Chhattisgarh Pilot (India): A Rs.10 crore setup proved that even smaller plants can affordably adopt hydrogen, achieving meaningful emission cuts (IGI Global, 2025).

These examples act like guiding lights, showing Indian cement manufacturers, that green hydrogen is both possible and practical. While European projects focus on large-scale, high-investment solutions, India’s pilots highlight cost-effective and scalable approaches—a model better suited for emerging economies.

Economic viability: Costs and benefits
Table 3 compares the major costs and benefits of adopting green hydrogen for a 1 MTPA cement plant.
Currently, hydrogen costs Rs.300–500/kg, compared to coal’s energy equivalent of ~Rs.30,000/tonne. While this looks expensive, incentives under the NGHM—including 50 per cent subsidies on electrolysers and carbon credits of Rs.2,000 per tonne CO2 avoided—help narrow the gap (MNRE, 2023). By 2035, hydrogen prices are expected to fall to Rs.150–200/kg, making it competitive with imported fossil fuels. According to IRENA (2022), this shift could save the global economy Rs.10–15 lakh crore by 2050.

Additional insights

  • A 1 MTPA cement plant switching fully to hydrogen could save ~0.32 million tonnes of CO2 annually. At Rs.2,000/tonne (carbon credit price), this alone brings Rs.64 crore/year in value.
  • Export markets (especially Europe) are introducing Carbon Border Adjustment Mechanisms (CBAMs), adding €60–70 per tonne of CO2 cost on imports. Early hydrogen adoption could save Indian exporters up to Rs.400–500 crore/year per large plant.
  • Long-term fuel independence: India imports 235 million tonnes of coal annually (MoC, 2024). Shifting 20 per cent of cement’s coal demand to hydrogen could save Rs.10,000+ crore/year in import bills.
  • ESG Ratings: Adoption strengthens sustainability scores, lowering financing costs. The World Bank estimates green financing can cut loan rates by 0.5–1 per cent, translating into Rs.25–30 crore savings annually for large plants.

Technical requirements: Installations and adjustments
Green hydrogen needs new setups and tweaks:

  • Electrolysers: 10 MW units (Rs.50–70 crore, half subsidized) produce hydrogen on-site, like a home generator.
  • Renewable energy: Solar/wind farms (Rs.100–150 crore) power electrolysis.
  • Storage and distribution: PESO-compliant tanks and pipelines (Rs.20–30 crore) ensure safety.
  • Kiln burner modifications: Retrofitting for hydrogen’s hotter flame (2000°C vs. coal’s 1400°C) costs Rs.10–20 crore, needing special nozzles, like upgrading a stove for a new fuel (CSTEP, 2025). Figure 2 shows these changes.
  • Pyro-Processing Adjustments: Pre-calciners are adjusted for hydrogen’s quick ignition, with oxygen injection boosting efficiency by 5–10 per cent (EnkiAI, 2025).

Phased implementation
Green hydrogen adoption in cement can move forward in three clear steps (see Figure 3):

  • Phase 1: Pilot Projects (2025–28) 5–10 plants set up small 5 MW electrolysers, solar farms, safe storage, and retrofit burners to use up to 10 per cent hydrogen. Training programs for workers ensure smooth adoption. Cost: Rs.500–1,000 crore, with 5–10 per cent emission reduction.
  • Phase 2: Scale-Up (2028–35) 50–70 plants expand to 10 MW electrolysers, bigger renewable farms, and pipelines. Full retrofits allow 30 per cent hydrogen use. Supported by Rs.12,500 crore in R&D incentives, costs stay manageable (~Rs.10,000 crore). Emissions fall 20–30 per cent.
  • Phase 3: Full Adoption (2035–50) Industry-wide transition with 20 MW electrolysers, renewable grids, and advanced storage. Backed by Rs.19,744 crore in incentives, the sector can cut emissions by 66–95 per cent and build a Rs.340 billion green market.
  • Step-by-step adoption—starting small, scaling up, and then going industry-wide—can make green hydrogen both practical and transformative for India’s cement industry.

Future outlook: Green cement pathway to 2050
Green hydrogen offers more than just emission cuts—it ensures steady kiln performance, lowers dust levels, and helps plants meet CPCB standards, saving Rs.1–2 crore per plant each year in health costs (TERI, 2024). On a larger scale, exporting green cement to markets such as Europe and Japan could generate around 3 lakh new jobs by 2030 and strengthen India’s global reputation for sustainability (IRENA, 2022).
Looking ahead, by 2035, most plants could be running on solar-powered hydrogen with zero-carbon kilns and smart CO2 monitoring systems, saving Rs.50–100 crore annually in penalties. By 2040, hydrogen prices may drop to Rs.100/kg, reducing cement production costs by 20–30 per cent. By 2050, hydrogen could fuel nearly 94 per cent of kilns, transforming India’s cement industry into a global leader in green manufacturing.
Green hydrogen is not just an alternative fuel—it is a game changer that can secure India’s economic growth, social wellbeing, and environmental future.

Conclusion
Green hydrogen—already tested by companies like Heidelberg in Germany and Adani in India—shows a clear path toward carbon-neutral cement. With government support through the NGHM and CPCB regulations, and a phased roadmap (pilots by 2028, scale-up by 2035, and full adoption by 2050), India has the chance to lead the global green transition. By investing Rs.100–200 crore per plant, cement manufacturers can build a cleaner, more sustainable future. The real question is: will they take action now?

References
• Cemex. (2020). Cemex advances toward carbon-neutral cement with hydrogen technology.
• CPCB. (2025). Classification of sectors into Red, Orange, Green, White, and Blue categories.
• CSTEP. (2025). Can hydrogen hasten the utilisation of alternative fuel resources in cement kilns?
• Devdiscourse. (2025). Adani’s cement giants lead India’s green transition with net-zero milestone.
• EnkiAI. (2025). Hydrogen in cement industry: Top 10 projects & companies.
• H2 Bulletin. (2024). Cement producers explore hydrogen to tackle emission.
• IBEF. (2025). Indian cement industry report. India Brand Equity Foundation.
• IEA. (2020). Cement technology roadmap: Low-carbon transition in the cement industry. International Energy Agency.
• IGI Global. (2025). Green hydrogen for cement production: A decarbonization pathway.
• IRENA. (2022). Green hydrogen cost reduction: Scaling up electrolysers. International Renewable Energy Agency.
• MNRE. (2023). National Green Hydrogen Mission. Ministry of New and Renewable Energy, Government of India.
• PESO. (2025). Guidelines for safe handling and storage of hydrogen. Petroleum and Explosives Safety Organisation.
• TERI. (2024). Decarbonizing India’s cement sector: Opportunities and challenges. The Energy and Resources Institute.
• UltraTech. (2024). Sustainability report 2024. UltraTech Cement Ltd.

ABOUT THE AUTHOR:
Dr SB Hegde is a Professor at Jain College of Engineering, Karnataka, and Visiting Professor at Pennsylvania State University, USA. With 248 publications and 10 patents, he specialises in low-carbon cement, Industry 4.0, and sustainability, consulting with cement companies to support India’s net zero goals.

 

 

Concrete

Refractory demands in our kiln have changed

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Radha Singh, Senior Manager (P&Q), Shree Digvijay Cement, points out why performance, predictability and life-cycle value now matter more than routine replacement in cement kilns.

As Indian cement plants push for higher throughput, increased alternative fuel usage and tighter shutdown cycles, refractory performance in kilns and pyro-processing systems is under growing pressure. In this interview, Radha Singh, Senior Manager (P&Q), Shree Digvijay Cement, shares how refractory demands have evolved on the ground and how smarter digital monitoring is improving kiln stability, uptime and clinker quality.

How have refractory demands changed in your kiln and pyro-processing line over the last five years?
Over the last five years, refractory demands in our kiln and pyro line have changed. Earlier, the focus was mostly on standard grades and routine shutdown-based replacement. But now, because of higher production loads, more alternative fuels and raw materials (AFR) usage and greater temperature variation, the expectation from refractory has increased.
In our own case, the current kiln refractory has already completed around 1.5 years, which itself shows how much more we now rely on materials that can handle thermal shock, alkali attack and coating fluctuations. We have moved towards more stable, high-performance linings so that we don’t have to enter the kiln frequently for repairs.
Overall, the shift has been from just ‘installation and run’ to selecting refractories that give longer life, better coating behaviour and more predictable performance under tougher operating conditions.

What are the biggest refractory challenges in the preheater, calciner and cooler zones?
• Preheater: Coating instability, chloride/sulphur cycles and brick erosion.
• Calciner: AFR firing, thermal shock and alkali infiltration.
• Cooler: Severe abrasion, red-river formation and mechanical stress on linings.
Overall, the biggest challenge is maintaining lining stability under highly variable operating conditions.

How do you evaluate and select refractory partners for long-term performance?
In real plant conditions, we don’t select a refractory partner just by looking at price. First, we see their past performance in similar kilns and whether their material has actually survived our operating conditions. We also check how strong their technical support is during shutdowns, because installation quality matters as much as the material itself.
Another key point is how quickly they respond during breakdowns or hot spots. A good partner should be available on short notice. We also look at their failure analysis capability, whether they can explain why a lining failed and suggest improvements.
On top of this, we review the life they delivered in the last few campaigns, their supply reliability and their willingness to offer plant-specific custom solutions instead of generic grades. Only a partner who supports us throughout the life cycle, which includes selection, installation, monitoring and post-failure analysis, fits our long-term requirement.

Can you share a recent example where better refractory selection improved uptime or clinker quality?
Recently, we upgraded to a high-abrasion basic brick at the kiln outlet. Earlier we had frequent chipping and coating loss. With the new lining, thermal stability improved and the coating became much more stable. As a result, our shutdown interval increased and clinker quality remained more consistent. It had a direct impact on our uptime.

How is increased AFR use affecting refractory behaviour?
Increased AFR use is definitely putting more stress on the refractory. The biggest issue we see daily is the rise in chlorine, alkalis and volatiles, which directly attack the lining, especially in the calciner and kiln inlet. AFR firing is also not as stable as conventional fuel, so we face frequent temperature fluctuations, which cause more thermal shock and small cracks in the lining.
Another real problem is coating instability. Some days the coating builds too fast, other days it suddenly drops, and both conditions impact refractory life. We also notice more dust circulation and buildup inside the calciner whenever the AFR mix changes, which again increases erosion.
Because of these practical issues, we have started relying more on alkali-resistant, low-porosity and better thermal shock–resistant materials to handle the additional stress coming from AFR.

What role does digital monitoring or thermal profiling play in your refractory strategy?
Digital tools like kiln shell scanners, IR imaging and thermal profiling help us detect weakening areas much earlier. This reduces unplanned shutdowns, helps identify hotspots accurately and allows us to replace only the critical sections. Overall, our maintenance has shifted from reactive to predictive, improving lining life significantly.

How do you balance cost, durability and installation speed during refractory shutdowns?
We focus on three points:
• Material quality that suits our thermal profile and chemistry.
• Installation speed, in fast turnarounds, we prefer monolithic.
• Life-cycle cost—the cheapest material is not the most economical. We look at durability, future downtime and total cost of ownership.
This balance ensures reliable performance without unnecessary expenditure.

What refractory or pyro-processing innovations could transform Indian cement operations?
Some promising developments include:
• High-performance, low-porosity and nano-bonded refractories
• Precast modular linings to drastically reduce shutdown time
• AI-driven kiln thermal analytics
• Advanced coating management solutions
• More AFR-compatible refractory mixes

These innovations can significantly improve kiln stability, efficiency and maintenance planning across the industry.

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Concrete

Digital supply chain visibility is critical

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MSR Kali Prasad, Chief Digital and Information Officer, Shree Cement, discusses how data, discipline and scale are turning Industry 4.0 into everyday business reality.

Over the past five years, digitalisation in Indian cement manufacturing has moved decisively beyond experimentation. Today, it is a strategic lever for cost control, operational resilience and sustainability. In this interview, MSR Kali Prasad, Chief Digital and Information Officer, Shree Cement, explains how integrated digital foundations, advanced analytics and real-time visibility are helping deliver measurable business outcomes.

How has digitalisation moved from pilot projects to core strategy in Indian cement manufacturing over the past five years?
Digitalisation in Indian cement has evolved from isolated pilot initiatives into a core business strategy because outcomes are now measurable, repeatable and scalable. The key shift has been the move away from standalone solutions toward an integrated digital foundation built on standardised processes, governed data and enterprise platforms that can be deployed consistently across plants and functions.
At Shree Cement, this transition has been very pragmatic. The early phase focused on visibility through dashboards, reporting, and digitisation of critical workflows. Over time, this has progressed into enterprise-level analytics and decision support across manufacturing and the supply chain,
with clear outcomes in cost optimisation, margin protection and revenue improvement through enhanced customer experience.
Equally important, digital is no longer the responsibility of a single function. It is embedded into day-to-day operations across planning, production, maintenance, despatch and customer servicing, supported by enterprise systems, Industrial Internet of Things (IIoT) data platforms, and a structured approach to change management.

Which digital interventions are delivering the highest ROI across mining, production and logistics today?
In a capital- and cost-intensive sector like cement, the highest returns come from digital interventions that directly reduce unit costs or unlock latent capacity without significant capex.
Supply chain and planning (advanced analytics): Tools for demand forecasting, S&OP, network optimisation and scheduling deliver strong returns by lowering logistics costs, improving service levels, and aligning production with demand in a fragmented and regionally diverse market.
Mining (fleet and productivity analytics): Data-led mine planning, fleet analytics, despatch discipline, and idle-time reduction improve fuel efficiency and equipment utilisation, generating meaningful savings in a cost-heavy operation.
Manufacturing (APC and process analytics): Advanced Process Control, mill optimisation, and variability reduction improve thermal and electrical efficiency, stabilise quality and reduce rework and unplanned stoppages.
Customer experience and revenue enablement (digital platforms): Dealer and retailer apps, order visibility and digitally enabled technical services improve ease of doing business and responsiveness. We are also empowering channel partners with transparent, real-time information on schemes, including eligibility, utilisation status and actionable recommendations, which improves channel satisfaction and market execution while supporting revenue growth.
Overall, while Artificial Intelligence (AI) and IIoT are powerful enablers, it is advanced analytics anchored in strong processes that typically delivers the fastest and most reliable ROI.

How is real-time data helping plants shift from reactive maintenance to predictive and prescriptive operations?
Real-time and near real-time data is driving a more proactive and disciplined maintenance culture, beginning with visibility and progressively moving toward prediction and prescription.
At Shree Cement, we have implemented a robust SAP Plant Maintenance framework to standardise maintenance workflows. This is complemented by IIoT-driven condition monitoring, ensuring consistent capture of equipment health indicators such as vibration, temperature, load, operating patterns and alarms.
Real-time visibility enables early detection of abnormal conditions, allowing teams to intervene before failures occur. As data quality improves and failure histories become structured, predictive models can anticipate likely failure modes and recommend timely interventions, improving MTBF and reducing downtime. Over time, these insights will evolve into prescriptive actions, including spares readiness, maintenance scheduling, and operating parameter adjustments, enabling reliability optimisation with minimal disruption.
A critical success factor is adoption. Predictive insights deliver value only when they are embedded into daily workflows, roles and accountability structures. Without this, they remain insights without action.

In a cost-sensitive market like India, how do cement companies balance digital investment with price competitiveness?
In India’s intensely competitive cement market, digital investments must be tightly linked to tangible business outcomes, particularly cost reduction, service improvement, and faster decision-making.
This balance is achieved by prioritising high-impact use cases such as planning efficiency, logistics optimisation, asset reliability, and process stability, all of which typically deliver quick payback. Equally important is building scalable and governed digital foundations that reduce the marginal cost of rolling out new use cases across plants.
Digitally enabled order management, live despatch visibility, and channel partner platforms also improve customer centricity while controlling cost-to-serve, allowing service levels to improve without proportionate increases in headcount or overheads.
In essence, the most effective digital investments do not add cost. They protect margins by reducing variability, improving planning accuracy, and strengthening execution discipline.

How is digitalisation enabling measurable reductions in energy consumption, emissions, and overall carbon footprint?
Digitalisation plays a pivotal role in improving energy efficiency, reducing emissions and lowering overall carbon intensity.
Real-time monitoring and analytics enable near real-time tracking of energy consumption and critical operating parameters, allowing inefficiencies to be identified quickly and corrective actions to be implemented. Centralised data consolidation across plants enables benchmarking, accelerates best-practice adoption, and drives consistent improvements in energy performance.
Improved asset reliability through predictive maintenance reduces unplanned downtime and process instability, directly lowering energy losses. Digital platforms also support more effective planning and control of renewable energy sources and waste heat recovery systems, reducing dependence on fossil fuels.
Most importantly, digitalisation enables sustainability progress to be tracked with greater accuracy and consistency, supporting long-term ESG commitments.

What role does digital supply chain visibility play in managing demand volatility and regional market dynamics in India?
Digital supply chain visibility is critical in India, where demand is highly regional, seasonality is pronounced, and logistics constraints can shift rapidly.
At Shree Cement, planning operates across multiple horizons. Annual planning focuses on capacity, network footprint and medium-term demand. Monthly S&OP aligns demand, production and logistics, while daily scheduling drives execution-level decisions on despatch, sourcing and prioritisation.
As digital maturity increases, this structure is being augmented by central command-and-control capabilities that manage exceptions such as plant constraints, demand spikes, route disruptions and order prioritisation. Planning is also shifting from aggregated averages to granular, cost-to-serve and exception-based decision-making, improving responsiveness, lowering logistics costs and strengthening service reliability.

How prepared is the current workforce for Industry 4.0, and what reskilling strategies are proving most effective?
Workforce preparedness for Industry 4.0 is improving, though the primary challenge lies in scaling capabilities consistently across diverse roles.
The most effective approach is to define capability requirements by role and tailor enablement accordingly. Senior leadership focuses on digital literacy for governance, investment prioritisation, and value tracking. Middle management is enabled to use analytics for execution discipline and adoption. Frontline sales and service teams benefit from
mobile-first tools and KPI-driven workflows, while shop-floor and plant teams focus on data-driven operations, APC usage, maintenance discipline, safety and quality routines.
Personalised, role-based learning paths, supported by on-ground champions and a clear articulation of practical benefits, drive adoption far more effectively than generic training programmes.

Which emerging digital technologies will fundamentally reshape cement manufacturing in the next decade?
AI and GenAI are expected to have the most significant impact, particularly when combined with connected operations and disciplined processes.
Key technologies likely to reshape the sector include GenAI and agentic AI for faster root-cause analysis, knowledge access, and standardisation of best practices; industrial foundation models that learn patterns across large sensor datasets; digital twins that allow simulation of process changes before implementation; and increasingly autonomous control systems that integrate sensors, AI, and APC to maintain stability with minimal manual intervention.
Over time, this will enable more centralised monitoring and management of plant operations, supported by strong processes, training and capability-building.

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Concrete

Cement Additives for Improved Grinding Efficiency

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Shreesh A Khadilkar discusses how advanced additive formulations allow customised, high-performance and niche cements—offering benefits while supporting blended cements and long-term cost and carbon reduction.

Cement additives are chemicals (inorganic and organic) added in small amounts (0.01 per cent to 0.2 per cent by weight) during cement grinding. Their main job? Reduce agglomeration, prevent pack-set, and keep the mill running smoother. Thus, these additions primarily improve, mill thru-puts, achieve lower clinker factor in blended cements PPC/PSC/PCC. Additionally, these additives improve concrete performance of cements or even for specific special premium cements with special USPs like lower setting times or for reduced water permeability in the resultant cement mortars and concrete (water repellent /permeation resistant cements), corrosion resistance etc.
The cement additives are materials which could be further differentiated as:

Grinding aids:
• Bottlenecks in cement grinding capacity, such materials can enhance throughputs
• Low specific electrical energy consumption during cement grinding
• Reduce “Pack set” problem and improve powder flowability

Quality improvers:
• Opportunity for further clinker factor reduction
• Solution for delayed cement setting or strength development issues at early or later ages.

Others: materials which are used for specific special cements with niche properties as discussed in the subsequent pages.
When cement additives are used as grinding aids or quality improvers, in general the additives reduce the inter-particle forces; reduce coating over grinding media and mill internals. Due to creation of like charges on cement particles, there is decreased agglomeration, much improved flowability, higher generation of fines better dispersion of particles in separator feed and reduction of mill filling level (decrease of residence time). However, in VRM grinding; actions need to be taken to have stable bed formation on the table.
It has been reported in literature and also substantiated by a number of detailed evaluations of different cement additive formulations in market, that the cement additive formulations are a combination of different chemical compounds, typically composed of:

  1. Accelerator/s for the hydration reaction of cements which are dependent on the acceleration effect desired in mortar compressive strengths at early or later ages, the choice of the materials is also dependent on clinker quality and blending components (flyash / slag) or a mix of both.
  2. Water reducer / workability / wet-ability enhancer, which would show impact on the resultant cement mortars and concrete. Some of the compounds (retarders) like polysaccharide derivatives, gluconates etc., show an initial retarding action towards hydration which result in reducing the water requirements for the cements thus act as water reducers, or it could be some appropriate polymeric molecules which show improved wet-ability and reduce water demand. These are selected based on the mineral component and type of cements (PPC/PSC /PCC).
  3. Grinding aids: Compounds that work as Grinding Aid i.e. which would enhance Mill thru-put on one hand as well as would increase the early strengths due to the higher fines generation/ or activation of cement components. These compounds could be like alkanol-amines such as TIPA, DEIPA, TEA etc. or could be compounds like glycols and other poly-ols, depending on whether it is OPC or PPC or PSC or PCC manufacture.

Mechanism of action — Step By Step—

  1. Reduce Agglomeration, Cement particles get electrostatically charged during grinding, stick together, form “flocs”, block mill efficiency, waste energy. Grinding aid molecules adsorb onto particle surfaces, neutralise charge, prevent re-agglomeration.
  2. Improve Powder Flowability, Adsorbed molecules create a lubricating layer, particles slide past each other easier, better mill throughput, less “dead zone” buildup.
    Also reduces caking on mill liners, diaphragms, and separator screens, less downtime for cleaning.
  3. Enhance Grinding Efficiency (Finer Product Faster), By preventing agglomeration, particles stay dispersed more surface area exposed to grinding media, finer grind achieved with same energy input, Or: same fineness achieved with less energy, huge savings.
    Example:
    • Without aid ? 3500 cm²/g Blaine needs 40 kWh/ton
    • With use of optimum grinding aid same fineness at 32 kWh/ton 20 per cent energy savings
  4. Reduce Pack Set and Silo Caking Grinding aids (GA) inhibit hydration of free lime (CaO) during storage prevents premature hardening or “pack set” in silos. especially critical in humid climates or with high free lime clinker.
    It may be stated here that Overdosing of GA can cause: – Foaming in mill (especially with glycols) reduces grinding efficiency, retardation of cement setting (especially with amines/acids), odor issues (in indoor mills) – Corrosion of mill components (if acidic aids used improperly)
    The best practice to optimise use of GA is Start with 0.02 per cent to 0.05 per cent dosage test fineness, flow, and set time adjust up/down. Due to static charge of particles, the sample may stick to the sides of sampler pipe and so sampling need to be properly done.
    Depending on type of cements i.e. OPC, PPC, PSC, PCC, the grinding aids combinations need to be optimised, a typical Poly carboxylate ether also could be a part of the combo grinding aids

Cement additives for niche properties of the cement in concrete.
The cement additives can also be tailor made to create specific niche properties in cements, OPC, PPC, PSC and PCC to create premium or special brands. The special niche properties of the cement being its additional USP of such cement products, and are useful for customers to build a durable concrete structure with increased service life.


Such properties could be:
• Additives for improved concrete performance of cements, high early strength in PPC/PSC/PCC, much reduced water demand in cement, cements with improved slump retentivity in concrete, self-compacting, self levelling in concrete, cements with improved adhesion property of the cement mortar
• Water repellence / water proofing, permeability resistance in mortars and concrete.
• Biocidal cement
• Photo catalytic cements
• Cements with negligible ASR reactions etc.

Additives for cements for improved concrete performance
High early strengths: Use of accelerators. These are chemical compounds which enhance the degree of hydration of cement. These can include setting or hardening accelerators depending on whether their action occurs in the plastic or hardened state respectively. Thus, the setting accelerators reduce the setting time, whereas the hardening accelerators increase the early age strengths. The setting accelerators act during the initial minutes of the cement hydration, whereas the hardening accelerators act mainly during the initial days of hydration.
Chloride salts are the best in class. However, use of chloride salts as hardening accelerators are strongly discouraged for their action in promoting the corrosion of rebar, thus, chloride-free accelerators are preferred. The hardening accelerators could be combinations of compounds like nitrate, nitrite and thiocyanate salts of alkali or alkaline earth metals or thiosulphate, formate, and alkanol amines depending on the cement types.
However, especially in blended cements (PPC/PSC/PCC the increased early strengths invariably decrease the 28 day strengths. These aspects lead to creating combo additives along with organic polymers to achieve improved early strengths as well as either same or marginally improved 28 days strengths with reduced clinker factor in the blended cement, special OPC with reduced admixture requirements. With use of appropriate combination of inorganic and organic additives we could create an OPC with substantially reduced water demand or improved slump retentivity. Use of such an OPC would show exceptional concrete performance in high grade concretes as it would exhibit lower admixture requirements in High Grade Concretes.
PPC with OPC like properties: With the above concept we could have a PPC, having higher percentage flyash, with a combo cement additive which would have with concrete performance similar to OPC in say M40/M50 concrete. Such a PPC would produce a high-strength PPC concrete (= 60 MPa @ 28d) + improved workability, durability and sustainability.
Another interesting aspect could also be of using ultrafine fine flyash /ultrafine slags as additions in OPC/PPC/PSC for achieving lower clinker factor as well as to achieve improved later age strengths with or without a combo cement additive.
The initial adhesion property at sites of especially PPC/PSC/PCC based mortars can be improved through use of appropriate organic polymers addition during the manufacture of these cements. Such cements would have a better adhesion property for plastering/brick bonding etc., as it has much lower rebound loss of their mortars in such applications.
It is needless to mention here that with use of additives, we could also have cement with viscosity modifying cement additives, for self-compaction and self-leveling concrete performance.
Use of Phosphogypsum retards the setting time of cements, we can use additive different additive combos to overcome retardation and improve the 1 day strengths of the cements and concretes.

About the author:
Shreesh Khadilkar, Consultant & Advisor, Former Director Quality & Product Development, ACC, a seasoned consultant and advisor, brings over 37 years of experience in cement manufacturing, having held leadership roles in R&D and product development at ACC Ltd. With deep expertise in innovative cement concepts, he is dedicated to sharing his knowledge and improving the performance of cement plants globally.

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