Economy & Market
Revival of small scale cement manufacturing
Published
7 years agoon
By
admin
The availability of most of the AFR is limited or scattered which may not be economically viable for use in most of the large cement plants because of logistics, quantity, preparation and technical issues, says Dr KN Bhattacharjee.
The availability of most of the AFR is limited or scattered, which may not be economically viable for use in most of the large cement plants because of logistics, quantity, preparation and technical issues. This is a great roadblock for the effective use of AFR. However if an industry can find means to utilise its own by-product or waste in its own premises or nearby then it will be a win- win situation for all. Cement manufacturing process is a very appropriate process to recycle many industrial and agricultural wastes. The black meal process of vertical shaft kiln technology is a proven technology in China and India and can serve as a very good outlet for consuming AFR in the vicinity of industries generating the waste in small quantities.
This will also help in reducing environmental pollution. The author has carried out numerous plant scale trials with various industrial and agricultural wastes in VSK plants in India with reasonable success and feels that it may be worthwhile to go backward technology-wise to improve India’s usage of AFR. With the recognition of performance-based cements in most of the standards of world, composite cements are to gain ground and many alternate materials mainly industrial wastes can find profitable use again in small-sized cement plants.
The vertical shaft kiln (VSK) technology is an old technology of Portland Cement manufacture and even the modern versions have almost phased out from India mainly because of economics of scale and taxation issues. In China, still 30 per cent of its cement production comes from shaft kiln plants. The VSK process technology is still a workable proposition for use of wastes available in limited quantities. Also by virtue of the simple process a plethora of process issues associated with modern pre-heater, pre-calciner rotary kiln system are eradicated while using AFR. Plant scale trials with many wastes have shown improvement in VSK clinker quality and better productivity from the kilns. Also it is possible to add many wastes in small quantities directly to VSK clinker to produce high performing composite cements. Although the plan sounds to be reverse engineering but sometimes an old concept can regain its past glory due to changing national needs and environmental issues.
The modern vertical shaft kiln technology is technically sound and institutes like National Council of Cement and Building Materials (NCCBM) and the then Regional Research Laboratory (RRL), Jorhat had done a commendable work in modernising the technology in India. Also the village-based Saboo technology created a stir in India in the 80s when they brought cement manufacturing under the umbrella of small scale industry. During that period, the objective was to increase production as India was cement deficit and VSK technology was a partial answer to quickly bridge the gap between demand and supply. In the hilly terrain of North East, it is still a viable proposition to use scattered small limestone deposits in the midst of logistical challenges.
The advantages and disadvantages of black meal process of vertical shaft kiln technology:
Advantages:
- Small scale cement production and still suitable in hilly terrains having limestone deposits for local distribution of cement.
- Energy efficient process: Specific heat consumption is in the range 600 to 650 Kcal/kg of clinker. Specific power consumption is in the range 0f 60 to 70 Kwh/tonne OPC although authentic figures are not available. Since drying, pre-heating, calcining, burning and cooling are integrated in the same vessel, heat losses due to convection and radiation is much reduced.
- Porous VSK clinker is much easier to grind thus cement grinding power requirement is less.
- Very low refractory consumption as kiln is stationery and low abrasion as material flow is vertically downward with slow speed.
- Vast scope of using AFR available in smaller quantities is the major advantage. Some alternate waste materials can act as flux or mineraliser. Mineralising ions can increase the rate of reaction in burning zone leading to complete burning in burning zone.
- Thus the technology offers avenue not only in the use of wastes but also utilise the waste in improving burnability by stabilising phases at lower temperatures.
- recirculation of obnoxious gases and materials which ensures smooth operation and higher productivity.
- Due a constant bed of wet green nodules above the calcining zone the green nodules bed acts as an effective filter to arrest all dust particles. No additional gas cleaning device is required.
- Since fuel is inter-ground with raw materials elaborate arrangement of fuel preparation and firing is eliminated
- Very effective and controlled flow of material through flat grate using variable frequency drive (VFD). This helps to position the burning zone constantly at the same level.
- Relatively simple machines to operate and maintain.
- Gestation period of starting a new plant is very low.
- No highly skilled manpower is required and local folk/plant staff can be easily trained for operations.
- Possible to manufacture a variety of clinkers and thereafter produce various kinds of low cost Portland cements.
- Very little chance of cold air in-leakages. Diversion of combustion air during clinker discharge has been ably dealt by either triple air locking arrangement or material block tube in the modern VSKs.
- Since each nodule has its independent fuel system significantly higher temperatures are not achieved leading to no issues of NOx.
Disadvantages:
- Viability can be at stake due to taxation policies and lower scale of operation. However if Government gives tax rebates on use of AFR the plants can be viable. Also it is possible to reduce cost of production by using low cost or free of cost non- conventional materials and waste fuels available locally. Maybe the savings can be shared with customers.
- Quality issues: Many believe that VSK clinker cannot be at par with modern rotary plant clinker. In this respect a few conflicting issues are prevalent. It is true that using the same raw materials and fuel the modern rotary clinker will be better performing especially the later age compressive strengths and soundness of cements produced. However the soft burnt nature of the VSK clinker opens up possibilities of addressing customer requirements of good early age compressive strength and early setting in the case of PPC and PSC. The author has found that early age compressive strengths and setting can be matched with modern plants while making PPC with a maximum of 30 per cent fly ash absorption. The Black meal process is capable of producing sound clinkers with less than 1.5 per cent free lime and 45 per cent C3S component. The author’s experience in few VSK plants in Jodhpur-Rajasthan region supports this viewpoint. Experiences with various limestone in Northern India and Bhutan reveals that the technology cannot tolerate high magnesia limestone primarily due to the absence of rapid cooling arrangement but adding certain industrial wastes with mineralising minor constituents gives amazing results in reducing or mitigating this deleterious effect.
- Consistency of clinker: Consistency does get affected if the raw mix is not well homogenised and nodulisation is not controlled. However these can be easily solved by using good homogenisation and blending techniques. Nodulisation can be automated to yield nodules of good strength. In some cases nodule strength can be improved by double nodulisation. Various industrial wastes like bagasse from sugar industry have been found to improve nodule strength together with bonus addition of heat value. Waste oils can be added at this stage to give very good results.
- Heat difference between the central and peripheral charge especially in the large dia kilns of 100 TPD per day can be a matter of concern in some cases depending of raw materials and fuels used. The 50 tonne/day Saboo shaft kiln design was found to very efficient in this respect. Crust formations were found to be minimal. Dustry clinker due to beta to gamma conversion of C2S is prevalent in few cases but can be eliminated by stabilisation of phases even with the inherent disadvantage of rapid or quench cooling.
Plant scale trials using various alternate materials and fuels:
Use of pond ash, bottom ash and boiler fired rice husk ash in a 50 TPD VSK plant in Kanpur Dehat, Uttar Pradesh: Both bottom and pond ash were procured from Panki Thermal power plant and were used as components of raw mix separately as a source of Silica and Alumina by partial replacement of plastic clay by 15 to 20 per cent. There was drop in free lime from 2.2 per cent to 1.8 per cent and the dust content in clinker reduced drastically. There was increase of 1.5 to 2.0 MPa in 3 days and 3 MPa in 28days compressive strength of 43 grade OPC. The pond and bottom ash had substantial carbon particles (LOI- 15 to 20 per cent) which added some heat value and perhaps the reactivity of the raw mix increased by the presence of some amount of reactive alumino-silicates. Indirect effects noticed was smooth kiln operations with a slight increase of production from the 50 TPD VSK. Pond ash which is generally wet can be added directly during nodulisation if a dosing arrangement is designed to avoid the drying operation. Boiler fired Rice Husk was tried in the same plant which gave very good results in improving clinker quality. The material was black in colour with LOI around 10 per cent indicating unburnt carbon which must have supplemented the heat input. It was possible to add rice husk as it is but plant scale trial was not attempted with the apprehension that the husk fibres may not give a homozenised mix in the existing raw grinding arrangement.
Use of Phosphorus furnace slag, alkali bypass dust and bag house dust from a Calcium Carbide plant: All these materials were tried with a contention to capitalise mineralising effect from the wastes due to some minor constituents or the presence of reactive silica or Alumina. Even granulated blast furnace slag (GBFS) was also tried. Improvements in kiln productivity and quality was noticed of clinker in most of the cases. In VSK operation any measure which goes to ensure completion of the reactions in the short burning zone will definitely go in improving clinker quality and smooth kiln operations. Appropriate raw mix fineness with correct proportioning of waste materials and fuels, homogenisation hold the key to success.
Additions of alternate waste materials with VSK clinker to make composite cements The future of cement making is composite cements. This not will helps to use some industrial or agricultural wastes in the final product but also help to improve performance of cements and reduce the carbon footprint. In many cases it can lead to low cost cements together with better performance.
Significant improvement was observed when 5 per cent bag house dust from a calcium carbide plant was added in a quaternary mix of 60 per cent Granulated Blast Furnace slag (GBFS) and 3 per cent gypsum using VSK clinker. Initial setting time was reduced from 180 minutes to 40 minutes when compared with plain control sample of PSC. There was an improvement of 2 MPa at 3 days and 28 days compressive strength was more or less the same. Quaternary blends using Alkali bypass dust and 60 to 70 per cent GBFS , gypsum and VSK clinker also performed well in terms of faster setting and improvement of early age compressive strength. Similar results were obtained while using brick kiln ash and calcined clay Pozzolana in dosages of 15 to 20 per cent while making PPC mixes using VSK clinker.
Thus VSK clinker can act as a performance enhancer for early setting and early age compressive strength in presence of high dosage GBFS containing PSC cements and fly ash/CCP based Pozzolanic cements. Hydration studies have revealed that the soft burnt VSK clinker releases soft burnt lime at a faster rate in the early ages leading to higher quantity hydration products both with GBFS and Pozzolana.
Conclusion
The author was associated with VSK plants for six years while doing his Ph.D. His doctoral work is mainly associated with hydration studies of composite cements and VSK clinker doped with ions coming from various industrial and agricultural wastes. He feels that the black meal process using modern vertical shaft kiln technology can be a viable proposition to use localised waste materials available in limited quantities. The process simplicity of the Black Meal process opens up immense potential for use of wastes (both agricultural and Industrial) with improved cement performance in many cases. Waste generating plants can have captive VSK plants or sub let this activity to local entrepreneurs. All performance enhancements have been validated by actual hydration studies which is available with the author for anyone who is interested. This has been a part of the author’s doctoral work. The author feels that for India till we incorporate large scale AFR facilities catering to large cement plants the VSK plants can be revived mainly for use of localised AFR as the project cost and gestation period from concept to commissioning is very low.
Acknowledgement
The author is grateful to AKS University administration for allowing to publish this paper.
About the author
Prof (Dr) KN Bhattacharjee has 37 years experience in the global cement industry. He has worked with all process technologies of cement manufacture and has done considerable work on use of AFR in mini-cement plants. His Ph.D thesis is in applied cement chemistry and his findings helped many mini-cement plants in India to improve their profitability during the late 80s. He has publications in reputed international and national journals like Cement and Concrete Research, ZKG International, Silicate Industrials, Transactions of Indian Ceramic Society, etc. After his retirement in 2016 from Dangote-Africa, he is teaching cement technology to B.Tech students in AKS University, Satna. Dr KNB has worked with ACC in India, two plants in Oman, Lafarge Canada and Dangote, Africa.
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Concrete
Refractory demands in our kiln have changed
Published
12 hours agoon
February 20, 2026By
admin
Radha Singh, Senior Manager (P&Q), Shree Digvijay Cement, points out why performance, predictability and life-cycle value now matter more than routine replacement in cement kilns.
As Indian cement plants push for higher throughput, increased alternative fuel usage and tighter shutdown cycles, refractory performance in kilns and pyro-processing systems is under growing pressure. In this interview, Radha Singh, Senior Manager (P&Q), Shree Digvijay Cement, shares how refractory demands have evolved on the ground and how smarter digital monitoring is improving kiln stability, uptime and clinker quality.
How have refractory demands changed in your kiln and pyro-processing line over the last five years?
Over the last five years, refractory demands in our kiln and pyro line have changed. Earlier, the focus was mostly on standard grades and routine shutdown-based replacement. But now, because of higher production loads, more alternative fuels and raw materials (AFR) usage and greater temperature variation, the expectation from refractory has increased.
In our own case, the current kiln refractory has already completed around 1.5 years, which itself shows how much more we now rely on materials that can handle thermal shock, alkali attack and coating fluctuations. We have moved towards more stable, high-performance linings so that we don’t have to enter the kiln frequently for repairs.
Overall, the shift has been from just ‘installation and run’ to selecting refractories that give longer life, better coating behaviour and more predictable performance under tougher operating conditions.
What are the biggest refractory challenges in the preheater, calciner and cooler zones?
• Preheater: Coating instability, chloride/sulphur cycles and brick erosion.
• Calciner: AFR firing, thermal shock and alkali infiltration.
• Cooler: Severe abrasion, red-river formation and mechanical stress on linings.
Overall, the biggest challenge is maintaining lining stability under highly variable operating conditions.
How do you evaluate and select refractory partners for long-term performance?
In real plant conditions, we don’t select a refractory partner just by looking at price. First, we see their past performance in similar kilns and whether their material has actually survived our operating conditions. We also check how strong their technical support is during shutdowns, because installation quality matters as much as the material itself.
Another key point is how quickly they respond during breakdowns or hot spots. A good partner should be available on short notice. We also look at their failure analysis capability, whether they can explain why a lining failed and suggest improvements.
On top of this, we review the life they delivered in the last few campaigns, their supply reliability and their willingness to offer plant-specific custom solutions instead of generic grades. Only a partner who supports us throughout the life cycle, which includes selection, installation, monitoring and post-failure analysis, fits our long-term requirement.
Can you share a recent example where better refractory selection improved uptime or clinker quality?
Recently, we upgraded to a high-abrasion basic brick at the kiln outlet. Earlier we had frequent chipping and coating loss. With the new lining, thermal stability improved and the coating became much more stable. As a result, our shutdown interval increased and clinker quality remained more consistent. It had a direct impact on our uptime.
How is increased AFR use affecting refractory behaviour?
Increased AFR use is definitely putting more stress on the refractory. The biggest issue we see daily is the rise in chlorine, alkalis and volatiles, which directly attack the lining, especially in the calciner and kiln inlet. AFR firing is also not as stable as conventional fuel, so we face frequent temperature fluctuations, which cause more thermal shock and small cracks in the lining.
Another real problem is coating instability. Some days the coating builds too fast, other days it suddenly drops, and both conditions impact refractory life. We also notice more dust circulation and buildup inside the calciner whenever the AFR mix changes, which again increases erosion.
Because of these practical issues, we have started relying more on alkali-resistant, low-porosity and better thermal shock–resistant materials to handle the additional stress coming from AFR.
What role does digital monitoring or thermal profiling play in your refractory strategy?
Digital tools like kiln shell scanners, IR imaging and thermal profiling help us detect weakening areas much earlier. This reduces unplanned shutdowns, helps identify hotspots accurately and allows us to replace only the critical sections. Overall, our maintenance has shifted from reactive to predictive, improving lining life significantly.
How do you balance cost, durability and installation speed during refractory shutdowns?
We focus on three points:
• Material quality that suits our thermal profile and chemistry.
• Installation speed, in fast turnarounds, we prefer monolithic.
• Life-cycle cost—the cheapest material is not the most economical. We look at durability, future downtime and total cost of ownership.
This balance ensures reliable performance without unnecessary expenditure.
What refractory or pyro-processing innovations could transform Indian cement operations?
Some promising developments include:
• High-performance, low-porosity and nano-bonded refractories
• Precast modular linings to drastically reduce shutdown time
• AI-driven kiln thermal analytics
• Advanced coating management solutions
• More AFR-compatible refractory mixes
These innovations can significantly improve kiln stability, efficiency and maintenance planning across the industry.
Concrete
Digital supply chain visibility is critical
Published
12 hours agoon
February 20, 2026By
admin
MSR Kali Prasad, Chief Digital and Information Officer, Shree Cement, discusses how data, discipline and scale are turning Industry 4.0 into everyday business reality.
Over the past five years, digitalisation in Indian cement manufacturing has moved decisively beyond experimentation. Today, it is a strategic lever for cost control, operational resilience and sustainability. In this interview, MSR Kali Prasad, Chief Digital and Information Officer, Shree Cement, explains how integrated digital foundations, advanced analytics and real-time visibility are helping deliver measurable business outcomes.
How has digitalisation moved from pilot projects to core strategy in Indian cement manufacturing over the past five years?
Digitalisation in Indian cement has evolved from isolated pilot initiatives into a core business strategy because outcomes are now measurable, repeatable and scalable. The key shift has been the move away from standalone solutions toward an integrated digital foundation built on standardised processes, governed data and enterprise platforms that can be deployed consistently across plants and functions.
At Shree Cement, this transition has been very pragmatic. The early phase focused on visibility through dashboards, reporting, and digitisation of critical workflows. Over time, this has progressed into enterprise-level analytics and decision support across manufacturing and the supply chain,
with clear outcomes in cost optimisation, margin protection and revenue improvement through enhanced customer experience.
Equally important, digital is no longer the responsibility of a single function. It is embedded into day-to-day operations across planning, production, maintenance, despatch and customer servicing, supported by enterprise systems, Industrial Internet of Things (IIoT) data platforms, and a structured approach to change management.
Which digital interventions are delivering the highest ROI across mining, production and logistics today?
In a capital- and cost-intensive sector like cement, the highest returns come from digital interventions that directly reduce unit costs or unlock latent capacity without significant capex.
Supply chain and planning (advanced analytics): Tools for demand forecasting, S&OP, network optimisation and scheduling deliver strong returns by lowering logistics costs, improving service levels, and aligning production with demand in a fragmented and regionally diverse market.
Mining (fleet and productivity analytics): Data-led mine planning, fleet analytics, despatch discipline, and idle-time reduction improve fuel efficiency and equipment utilisation, generating meaningful savings in a cost-heavy operation.
Manufacturing (APC and process analytics): Advanced Process Control, mill optimisation, and variability reduction improve thermal and electrical efficiency, stabilise quality and reduce rework and unplanned stoppages.
Customer experience and revenue enablement (digital platforms): Dealer and retailer apps, order visibility and digitally enabled technical services improve ease of doing business and responsiveness. We are also empowering channel partners with transparent, real-time information on schemes, including eligibility, utilisation status and actionable recommendations, which improves channel satisfaction and market execution while supporting revenue growth.
Overall, while Artificial Intelligence (AI) and IIoT are powerful enablers, it is advanced analytics anchored in strong processes that typically delivers the fastest and most reliable ROI.
How is real-time data helping plants shift from reactive maintenance to predictive and prescriptive operations?
Real-time and near real-time data is driving a more proactive and disciplined maintenance culture, beginning with visibility and progressively moving toward prediction and prescription.
At Shree Cement, we have implemented a robust SAP Plant Maintenance framework to standardise maintenance workflows. This is complemented by IIoT-driven condition monitoring, ensuring consistent capture of equipment health indicators such as vibration, temperature, load, operating patterns and alarms.
Real-time visibility enables early detection of abnormal conditions, allowing teams to intervene before failures occur. As data quality improves and failure histories become structured, predictive models can anticipate likely failure modes and recommend timely interventions, improving MTBF and reducing downtime. Over time, these insights will evolve into prescriptive actions, including spares readiness, maintenance scheduling, and operating parameter adjustments, enabling reliability optimisation with minimal disruption.
A critical success factor is adoption. Predictive insights deliver value only when they are embedded into daily workflows, roles and accountability structures. Without this, they remain insights without action.
In a cost-sensitive market like India, how do cement companies balance digital investment with price competitiveness?
In India’s intensely competitive cement market, digital investments must be tightly linked to tangible business outcomes, particularly cost reduction, service improvement, and faster decision-making.
This balance is achieved by prioritising high-impact use cases such as planning efficiency, logistics optimisation, asset reliability, and process stability, all of which typically deliver quick payback. Equally important is building scalable and governed digital foundations that reduce the marginal cost of rolling out new use cases across plants.
Digitally enabled order management, live despatch visibility, and channel partner platforms also improve customer centricity while controlling cost-to-serve, allowing service levels to improve without proportionate increases in headcount or overheads.
In essence, the most effective digital investments do not add cost. They protect margins by reducing variability, improving planning accuracy, and strengthening execution discipline.
How is digitalisation enabling measurable reductions in energy consumption, emissions, and overall carbon footprint?
Digitalisation plays a pivotal role in improving energy efficiency, reducing emissions and lowering overall carbon intensity.
Real-time monitoring and analytics enable near real-time tracking of energy consumption and critical operating parameters, allowing inefficiencies to be identified quickly and corrective actions to be implemented. Centralised data consolidation across plants enables benchmarking, accelerates best-practice adoption, and drives consistent improvements in energy performance.
Improved asset reliability through predictive maintenance reduces unplanned downtime and process instability, directly lowering energy losses. Digital platforms also support more effective planning and control of renewable energy sources and waste heat recovery systems, reducing dependence on fossil fuels.
Most importantly, digitalisation enables sustainability progress to be tracked with greater accuracy and consistency, supporting long-term ESG commitments.
What role does digital supply chain visibility play in managing demand volatility and regional market dynamics in India?
Digital supply chain visibility is critical in India, where demand is highly regional, seasonality is pronounced, and logistics constraints can shift rapidly.
At Shree Cement, planning operates across multiple horizons. Annual planning focuses on capacity, network footprint and medium-term demand. Monthly S&OP aligns demand, production and logistics, while daily scheduling drives execution-level decisions on despatch, sourcing and prioritisation.
As digital maturity increases, this structure is being augmented by central command-and-control capabilities that manage exceptions such as plant constraints, demand spikes, route disruptions and order prioritisation. Planning is also shifting from aggregated averages to granular, cost-to-serve and exception-based decision-making, improving responsiveness, lowering logistics costs and strengthening service reliability.
How prepared is the current workforce for Industry 4.0, and what reskilling strategies are proving most effective?
Workforce preparedness for Industry 4.0 is improving, though the primary challenge lies in scaling capabilities consistently across diverse roles.
The most effective approach is to define capability requirements by role and tailor enablement accordingly. Senior leadership focuses on digital literacy for governance, investment prioritisation, and value tracking. Middle management is enabled to use analytics for execution discipline and adoption. Frontline sales and service teams benefit from
mobile-first tools and KPI-driven workflows, while shop-floor and plant teams focus on data-driven operations, APC usage, maintenance discipline, safety and quality routines.
Personalised, role-based learning paths, supported by on-ground champions and a clear articulation of practical benefits, drive adoption far more effectively than generic training programmes.
Which emerging digital technologies will fundamentally reshape cement manufacturing in the next decade?
AI and GenAI are expected to have the most significant impact, particularly when combined with connected operations and disciplined processes.
Key technologies likely to reshape the sector include GenAI and agentic AI for faster root-cause analysis, knowledge access, and standardisation of best practices; industrial foundation models that learn patterns across large sensor datasets; digital twins that allow simulation of process changes before implementation; and increasingly autonomous control systems that integrate sensors, AI, and APC to maintain stability with minimal manual intervention.
Over time, this will enable more centralised monitoring and management of plant operations, supported by strong processes, training and capability-building.
Concrete
Cement Additives for Improved Grinding Efficiency
Published
12 hours agoon
February 20, 2026By
admin
Shreesh A Khadilkar discusses how advanced additive formulations allow customised, high-performance and niche cements—offering benefits while supporting blended cements and long-term cost and carbon reduction.
Cement additives are chemicals (inorganic and organic) added in small amounts (0.01 per cent to 0.2 per cent by weight) during cement grinding. Their main job? Reduce agglomeration, prevent pack-set, and keep the mill running smoother. Thus, these additions primarily improve, mill thru-puts, achieve lower clinker factor in blended cements PPC/PSC/PCC. Additionally, these additives improve concrete performance of cements or even for specific special premium cements with special USPs like lower setting times or for reduced water permeability in the resultant cement mortars and concrete (water repellent /permeation resistant cements), corrosion resistance etc.
The cement additives are materials which could be further differentiated as:
Grinding aids:
• Bottlenecks in cement grinding capacity, such materials can enhance throughputs
• Low specific electrical energy consumption during cement grinding
• Reduce “Pack set” problem and improve powder flowability
Quality improvers:
• Opportunity for further clinker factor reduction
• Solution for delayed cement setting or strength development issues at early or later ages.
Others: materials which are used for specific special cements with niche properties as discussed in the subsequent pages.
When cement additives are used as grinding aids or quality improvers, in general the additives reduce the inter-particle forces; reduce coating over grinding media and mill internals. Due to creation of like charges on cement particles, there is decreased agglomeration, much improved flowability, higher generation of fines better dispersion of particles in separator feed and reduction of mill filling level (decrease of residence time). However, in VRM grinding; actions need to be taken to have stable bed formation on the table.
It has been reported in literature and also substantiated by a number of detailed evaluations of different cement additive formulations in market, that the cement additive formulations are a combination of different chemical compounds, typically composed of:
- Accelerator/s for the hydration reaction of cements which are dependent on the acceleration effect desired in mortar compressive strengths at early or later ages, the choice of the materials is also dependent on clinker quality and blending components (flyash / slag) or a mix of both.
- Water reducer / workability / wet-ability enhancer, which would show impact on the resultant cement mortars and concrete. Some of the compounds (retarders) like polysaccharide derivatives, gluconates etc., show an initial retarding action towards hydration which result in reducing the water requirements for the cements thus act as water reducers, or it could be some appropriate polymeric molecules which show improved wet-ability and reduce water demand. These are selected based on the mineral component and type of cements (PPC/PSC /PCC).
- Grinding aids: Compounds that work as Grinding Aid i.e. which would enhance Mill thru-put on one hand as well as would increase the early strengths due to the higher fines generation/ or activation of cement components. These compounds could be like alkanol-amines such as TIPA, DEIPA, TEA etc. or could be compounds like glycols and other poly-ols, depending on whether it is OPC or PPC or PSC or PCC manufacture.
Mechanism of action — Step By Step—
- Reduce Agglomeration, Cement particles get electrostatically charged during grinding, stick together, form “flocs”, block mill efficiency, waste energy. Grinding aid molecules adsorb onto particle surfaces, neutralise charge, prevent re-agglomeration.
- Improve Powder Flowability, Adsorbed molecules create a lubricating layer, particles slide past each other easier, better mill throughput, less “dead zone” buildup.
Also reduces caking on mill liners, diaphragms, and separator screens, less downtime for cleaning. - Enhance Grinding Efficiency (Finer Product Faster), By preventing agglomeration, particles stay dispersed more surface area exposed to grinding media, finer grind achieved with same energy input, Or: same fineness achieved with less energy, huge savings.
Example:
• Without aid ? 3500 cm²/g Blaine needs 40 kWh/ton
• With use of optimum grinding aid same fineness at 32 kWh/ton 20 per cent energy savings - Reduce Pack Set and Silo Caking Grinding aids (GA) inhibit hydration of free lime (CaO) during storage prevents premature hardening or “pack set” in silos. especially critical in humid climates or with high free lime clinker.
It may be stated here that Overdosing of GA can cause: – Foaming in mill (especially with glycols) reduces grinding efficiency, retardation of cement setting (especially with amines/acids), odor issues (in indoor mills) – Corrosion of mill components (if acidic aids used improperly)
The best practice to optimise use of GA is Start with 0.02 per cent to 0.05 per cent dosage test fineness, flow, and set time adjust up/down. Due to static charge of particles, the sample may stick to the sides of sampler pipe and so sampling need to be properly done.
Depending on type of cements i.e. OPC, PPC, PSC, PCC, the grinding aids combinations need to be optimised, a typical Poly carboxylate ether also could be a part of the combo grinding aids
Cement additives for niche properties of the cement in concrete.
The cement additives can also be tailor made to create specific niche properties in cements, OPC, PPC, PSC and PCC to create premium or special brands. The special niche properties of the cement being its additional USP of such cement products, and are useful for customers to build a durable concrete structure with increased service life.
Such properties could be:
• Additives for improved concrete performance of cements, high early strength in PPC/PSC/PCC, much reduced water demand in cement, cements with improved slump retentivity in concrete, self-compacting, self levelling in concrete, cements with improved adhesion property of the cement mortar
• Water repellence / water proofing, permeability resistance in mortars and concrete.
• Biocidal cement
• Photo catalytic cements
• Cements with negligible ASR reactions etc.
Additives for cements for improved concrete performance
High early strengths: Use of accelerators. These are chemical compounds which enhance the degree of hydration of cement. These can include setting or hardening accelerators depending on whether their action occurs in the plastic or hardened state respectively. Thus, the setting accelerators reduce the setting time, whereas the hardening accelerators increase the early age strengths. The setting accelerators act during the initial minutes of the cement hydration, whereas the hardening accelerators act mainly during the initial days of hydration.
Chloride salts are the best in class. However, use of chloride salts as hardening accelerators are strongly discouraged for their action in promoting the corrosion of rebar, thus, chloride-free accelerators are preferred. The hardening accelerators could be combinations of compounds like nitrate, nitrite and thiocyanate salts of alkali or alkaline earth metals or thiosulphate, formate, and alkanol amines depending on the cement types.
However, especially in blended cements (PPC/PSC/PCC the increased early strengths invariably decrease the 28 day strengths. These aspects lead to creating combo additives along with organic polymers to achieve improved early strengths as well as either same or marginally improved 28 days strengths with reduced clinker factor in the blended cement, special OPC with reduced admixture requirements. With use of appropriate combination of inorganic and organic additives we could create an OPC with substantially reduced water demand or improved slump retentivity. Use of such an OPC would show exceptional concrete performance in high grade concretes as it would exhibit lower admixture requirements in High Grade Concretes.
PPC with OPC like properties: With the above concept we could have a PPC, having higher percentage flyash, with a combo cement additive which would have with concrete performance similar to OPC in say M40/M50 concrete. Such a PPC would produce a high-strength PPC concrete (= 60 MPa @ 28d) + improved workability, durability and sustainability.
Another interesting aspect could also be of using ultrafine fine flyash /ultrafine slags as additions in OPC/PPC/PSC for achieving lower clinker factor as well as to achieve improved later age strengths with or without a combo cement additive.
The initial adhesion property at sites of especially PPC/PSC/PCC based mortars can be improved through use of appropriate organic polymers addition during the manufacture of these cements. Such cements would have a better adhesion property for plastering/brick bonding etc., as it has much lower rebound loss of their mortars in such applications.
It is needless to mention here that with use of additives, we could also have cement with viscosity modifying cement additives, for self-compaction and self-leveling concrete performance.
Use of Phosphogypsum retards the setting time of cements, we can use additive different additive combos to overcome retardation and improve the 1 day strengths of the cements and concretes.
About the author:
Shreesh Khadilkar, Consultant & Advisor, Former Director Quality & Product Development, ACC, a seasoned consultant and advisor, brings over 37 years of experience in cement manufacturing, having held leadership roles in R&D and product development at ACC Ltd. With deep expertise in innovative cement concepts, he is dedicated to sharing his knowledge and improving the performance of cement plants globally.
Refractory demands in our kiln have changed
Digital supply chain visibility is critical
Redefining Efficiency with Digitalisation
Cement Additives for Improved Grinding Efficiency
Digital Pathways for Sustainable Manufacturing
Refractory demands in our kiln have changed
Digital supply chain visibility is critical
Redefining Efficiency with Digitalisation
Cement Additives for Improved Grinding Efficiency
Digital Pathways for Sustainable Manufacturing
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