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Utilisation of High Silica Low Grade Limestone

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With depletion of high cement grade limestone, [presently] Indian cement industry is facing an acute cement raw material problem for smooth plant operation and manufacture of higher grades of cement. Although India is bestowed with huge limestone deposits but most of the deposits in India presently available for cement manufacture are either marginal grade or low grade.The situation is further aggravated due to allocation of low grade coal to the cement industries. Some of the cement plants start with a simple limestone deposit with more or less uniform quality of limestone however with the consumption of the high grade limestone, the deposits are converted into intricate leaving behind low heterogeneous grade.

Hence urgently a serious thought is essential not only for detailed exploration of limestone deposits to convert the resources to reserves (as per UNFC), but also for development of a cost- effective dry beneficiation techniques for up gradation of low and sub-marginal grade high siliceous limestone in India for production of quality cements.

Scenario of limestone deposits in India
Limestone is the basic raw materials for cement manufacture and the growth of the cement industry depends on the availability of right grade cement grade limestone. India is having huge limestone deposits distributed throughout the geological stratigraphic horizon starting from Archaean to tertiary formations. The quality variation of limestone from deposit to deposit is very wide in India. The geographical distribution of limestone deposits in India is also not uniform. Some states do not have any limestone deposits.

Around 95 per cent of cement grade limestone deposits are concentrated in 10 states, although the cement grade limestone is occurring in 23 States in India in smaller quantities. Limestone deposits have not been reported from states like Punjab, Mizoram, Goa, Sikkim and Tripura. Whereas Haryana, Manipur, West Bengal, Andaman and Nicobar Islands have very meager reserves not suitable for large capacity cement plants. Based on the prima-facie availability of freehold cement grade limestone deposits, there is very limited scope for further addition of cement manufacturing capacity in the state of Kerala, Tamil Nadu, Bihar, Uttar Pradesh and Odisha. However, the States of Andhra Pradesh, Telangana, Assam, Gujarat, Himachal Pradesh, Karnataka, Chattisgarh, Meghalaya and Rajasthan have potential for further creation of cement manufacturing capacity.

The qualitative and quantitative assessment of limestone deposits have been carried out by various Central Government agencies, State Directorate of Geology and Mining and private companies. Based on the exploration data generated by these agencies at present the total cement limestone resource as estimated by Indian Bureau of Mines (IBM) is 124,539.551 million tonnes (MT). The zone wise and state wise cement grade limestone reserves and resources as per IBM are as under: Regarding quality of limestone, except limestone occurring in the North – Eastern states, Gujarat, few patches of Andhra Pradesh, Telangana, Rajasthan and Madhya Pradesh most of the deposits are low grade, either having high silica content (SiO2 16-20 per cent) or high magnesia containing 6-12 per cent MgO or even more. In this article only high silica low grade limestone will be discussed. In the March, 2018 issue we have discussed in detail about the use of high Magnesia Limestone in India.These limestone cannot be used for manufacture of cement as such and would need beneficiation.

Further, out of total limestone resources of 124539.91 MT, 30 per cent falls under the forest cover, restricted area and eco-sensitive zones, and hence not permissible for exploitation. As a result further 34677.19 million tonnes of limestone are not available for the cement industries, although some of the deposits are very good cement grade limestone. Hence from the available remaining 89862.361 Mts. limestone resources, cement grade limestone reserve is only 8948.926 MT (UNFC Code (111),(121) and (122)) as per UNFC classification of mineral deposits.

Although the consumption ratio of limestone to cement has gone down in India due to production of more blended cements, the limestone quantity requirement for cement manufacture has increased 1.5 times in last 15 years. Further the demand for high grade limestone has also increased due to production of more 43 and 53 grade OPC. It has been observed that the demand of high grade limestone further increases the mines rejects in case of low to marginal grade limestone deposits. The limestone requirement for production of 71.28 MT of clinker during 1997-98 was 106.92 MT and in the year 2016-17 it has enhanced to 300.00 MT. From an estimate it has been seen that for production of 500 MT of clinker ( as anticipated) by the end of 2020 the limestone requirement will be around 700 MT.

Sustainable Development Of Limestone Deposits
From an estimate it has been observed that with the present rate of consumption of available limestone reserves of India can sustain only 40 years. More over the low grade limestone deposits during mining is generating huge mine rejects during exploitation creating a major environmental problem. To overcome such problems the following actions are essential for trouble free operation of cement plants in India. Establishment of limestone reserves: It is the imperative need that government and private sector should go for massive exploration activity and establish and convert the inferred grade of limestone into measured grade. The will help the cement industry to plan to meet the future requirements. The systematic exploration activity and computerised deposit evaluation will help the development of accurate deposit model. The computerised 3-D deposit model for the each and every deposit is essential for planning of mining which will help in utilisation of low grade limestone and even the mine rejects in cement production as additives.

Systematic deposit exploitation plan: There are various methods adopted by the Indian cement industry presently to utilise the low grade limestone for cement manufacture. The computerised mine planning, pit head quality control, multimine scheduling are very effective techniques for blending of low and high grade limestone. This enhances the utilisation of low grade limestone to some extent. In spite of these techniques a considerable quantity of quarry rejects are generated every year, which has no use and creating additional environmental problem.

In India most of the cement plants are operating on heterogeneous intricate limestone deposits with the result that mine reject generation is high. Besides low grade its variability is extremely high due to intercalation of clay, pegmatite, schist etc. Therefore, the computerised mine planning with pit head quality control provides an elegant solution to utilise low grade limestone.

The mine planning software documents the deposit exploration data systematically, estimate the grade ? tonnage to higher degree of confidence level. It creates accurate deposit inventory with various deposit graphics. The multiple blending options of estimated deposit block not only helps in production of homogeneous raw materials but also enhance the quarry life. The block model concept created by Surpac/Datamine not only provides exhaustive information about the deposit but also forms the basis of mine scheduling offering flexibility in mining with multiple blending options. This can be one of the steps towards the judicial use of the limestone and conservation of national inventory of cement and high grade limestone.

Remote quarry management: Conservation of high grade, optimal use of low and marginal grade limestone is now possible by IT enabled technology supported by state of art mining softwares to monitor quarry operations. Lafarge Kamloops plant in BC, Canada was doomed to be exhausted of cement grade deposit in its existing quarry way back in 2012. Lafarge Technical Centre(CTS) in Montreal stepped in and by remote management established that there is enough limestone to run the plant for another 10 years from the same running quarry.

CTS monitored regularly the bore hole results which was sent to them before a blast and the results of blasts was monitored online from a Cross-belt analyser through VPN. A dedicated highly experienced geologist was made the champion of Kamloops plant. He could guide the plant mining contractor on the areas to be taken up for blasting well in advance. He had full information of exploration data, quarry hardware and plant requirements in terms of quality and quantity. He used the block model and pit design technique using sophisticated softwares and guided the contractor regularly ensuring high grade is conserved and low and sub marginal grade limestone used optimally. He visits the quarry only once in six months for detailed surveys and upgrades the data in software.

Holtec India has reported extension of limestone quarry belonging to a cement plant in North Ethopia by 16 years using this concept of remote quarry management. This should work out well with the Indian cement plants too. The local mines teams in most of the plants may not have the knowledge or expertise to use IT enabled modern technology with an array of softwares. Moreover there could be short cuts in local operation which kills the concept of conservation of high grade limestone. With the pressure of enhanced production in plants and generally with limited resources the long term mine planning is jeopardised leading to an unsustainable situation. Thus the remote quarry management model can be the best business model for mining management in Indian Cement Industry for sustainability.

An external unbiased eye equipped with all modern techniques can do wonders especially for plants in a group with remote monitoring from their technical centre or a central location in a cluster.

Bulk or cross belt analyser based on Prompt Gamma Neutron Activation analysis (PGNAA) is proving to be an useful tool in increasing quarry life by effective blending of various grades of limestone in intricate quarries. Since limestone analysis is available every minute after crusher this technique also helps in validation of the block model. Latest version of this equipment with upgraded software also help in pile management and control. This equipment is a must for intricate and heterogenous quarries to extend quarry life.

Beneficiation of low grade high silica limestone: To make use of low grade high siliceous limestone various beneficiation techniques have been tried by number of R&D institutions and industries. With the present day dry process manufacturing technology the wet beneficiation technology such as froth flotation method and semi wet process like bacterial leaching are not cost effective. Dry beneficiation is only suitable for the present day manufacturing technology of Portland cement clinker. Some of the dry process techniques are showing excellent result in lab scale studies but unfortunately not yet cost effective. Further studies and establishment of potential techniques is the need of the hour to conserve the limestone deposits. Some studies carried out to upgrade high siliceous limestone are given below.

In case of low grade siliceous limestone deposits most of the plant are using the crossing and screening techniques to separate the interstitial clay and impurities associated with the limestone to some extent. If the clay content is more some times washing is more beneficial. Before adoption of such technique a detailed study on the impurities associated with the limestone is essential. A liberation study is required to find out at what size fraction the impurities are separating from the limestone otherwise while separating a considerable good grade limestone may be lost. This study can starts with petrographic analysis of the limestone and impurities .With the petrographic analysis data, lab scale analysis is essential to establish the technique suitable for separation of impurities as the nature of the impurities and limestone varies from deposit to deposit.

Case study
The limestone deposit of this case study belongs to geologically Delhi Super Group. The formations are consist of mainly calcareous meta-sediments viz., calc-gneisses, calc-schists and calcitic limestone with minor bands of schist and quartzite. Considerable amount of limestone reserve is 38- 40 per cent CaO with Silica about 16-18 per cent. It was observed during exploration drilling that the core recovery is varying because of intercalation of clay, phylite etc. The intercalation clay is soft and fine grained where as the limestone is medium grained and hard. This has been confirmed by the petrographic study of the limestone deposit. Laboratory study indicates that the size fraction below 10mm is mostly clay and phylites. With the screening of clay and phylites the silica in limestone reduced from 16.66 per cent to 13.10 per cent and CaO enhanced from 38 per cent to 42 per cent making the limestone blendable. A double deck screen section is provided in this case in the crusher plant, -75mm limestone along with the clay goes directly to the screening plant section prior to crushing. On screening this material the -10mm fraction is rejected as it is mainly clay whereas the +10mm materials goes to the raw material stacker.

The size fraction of liberation varies from deposit to deposit depends on the grain size of limestone and physical quality of impurities. A thorough petrographic study is needed for best screening result.

For beneficiation of coarse grained high silica limestone, a study has been tried through differential grinding technique and results are as given in table-2. The grain size of quartz and calcite in the limestone under study is around 2 ? 150 ?m and the chemical composition is 15.90 per cent (SiO2) and 43.26 per cent (CaO) respectively. From the results of this study it has been observed that this technique has potentiality to reduce silica from limestone economically. However, in case of the fine grained limestone it is required to grind the material finer which involves high energy consumption.

Among all the electronic ore sorter developed, optical sorting is a highly potential technique and can be used for beneficiation of limestone having impurities with significant color difference such as amphibolites, pyroxenes etc. This technique has already been adopted in one of the cement plants in India and the plant has reported encouraging results.

It has been observed that quartz and dolomites are weakly magnetic with relative attractivity of 0.37 and 0.22 respectively, whereas calcite is non-magnetic with relative attractivity of 0.03. Hence, with high magnetic separator the silica and dolomite can be effectively separated from limestone. In case of electrostatic separation, it is difficult to separate the calcite and silica as they have almost same relative empirical conductivity (voltage-10,920). Whereas the relative empirical conductivity of Dolomite (voltage-8,268) is much lower than the calcite and quartz, as a result the dolomite crystals can be effectively separated from limestone by electrostatic separation methods.

The separation of silica and calcite by air classifier is also a very effective technique. Calcites (CaCO3), being lower in specific gravity than the silica (SiO2) are collected as overflow. In one case of a siliceous limestone this technique has been tried and the CaO in the limestone got enriched from 34.19 per cent to 44.23 per cent and also reduced silica considerably (Table-3). In case of separation of dolomite and calcite it is more effective as the specific gravity difference is higher.

Use of high calorific low ash fuel
Further the use of high silica limestone became difficult for production quality clinker with the Indian coal allocated to the cement industry. These coals are low grade with ash content as high as 35 per cent. During pyro-processing the absorption of coal ash increase the silica content in the raw meal making it difficult for production of quality clinker. In case of where high silica limestone is to be used, Pet coke and lignite are the best fuels to control the silica content. Although these fuels are have high sulfur content which can be controlled by maintaining alkali-sulphur ratio close to one.

Alternate cementitious production from low and marginal grade limestone
Manufacture of Sulpho-aluminate belite cement: In recent years Sulfo-Aluminate-Belite cement is receiving a lot of interest as it can be manufactured from various industrial wastes and low grade limestone. It is environmental friendly and requires less thermal energy for manufacture compared to OPC clinker manufacture.

Raw mixes for C4A3S clinker differ from the Portland cement as they contain significant amount of sulphate. Therefore, the reactions and product are quite different from those normally found in Portland cement production. The total lime requirement for production of such cement is less than 50 wt. per cent as against the about 65 wt. per cent for Portland cement. This indicates that for production of Sulfo- Aluminate Belite cement low grade limestone is suitable. The Sulfo-Aluminate Belite clinker can be produced by burning limestone, bauxite and gypsum at around 12000C. For production of Sulfo-Aluminate Belite cement the Lime Saturation Factor (LSF) requirement is low around 0.67, which reduces the consumption of limestone stone in manufacture. As the consumption of lime is less, the manufacture of this type of cement leads to around 35 per cent less CO2 than Portland cement. The requirement of thermal energy for production of Sulfo-Aluminate Belite clinker is also much less than the Portland cement clinker as it is manufactured at 12000C. It has been found that the Sulfo-Aluminate Belite is having very good dimensional stability, sulfate resistance, compressive strength development and better resistance to atmospheric carbonation comparable to commercial Portland cement. Presently these cements are produced commercially in countries such as China, Japan, Russia etc. successfully. These cements are best suitable for the construction in the coastal areas owing to their better sulphate resistance property.

Sulfo-Aluminates Belite Cement contains C4A3S as main component together with Calcium Sulfate, Dicalcium Silicate (C2S), Tetracalcium Iron Aluminate (C4AF), Calcium Aluminate (C3A,CA,&C12A7) and Silicoaluminates (C2AS, CAS3). The mineralogical composition of the Sulfo-Aluminate Belite cement are quite different than the Portland cement ( Table -4) as it contains relatively high concentration of C2S, C4A3S and C4AF, shows different properties during hydration. Chemical composition of Sulfo-Aluminate Belite cement is markedly different from the Portland cement. A comparison of chemical composition and properties of typical Portland cement and Sulfo-Aluminate Belite cement is given in table-5.

The rapid setting of Sulfo-Aluminate cement is mainly due to quick conversion of C4A3S to hydration product during early age hydration. On hydration the gypsum reacts with C4A3S and from ettringite (C6AS3H32). This regulates the technical properties of Sulfo-Aluminate Belite cement.

4 CaO3Al2O3SO3+8CaSO4+6CaO+93H2O ? 3 (CaOAl2O3CaSO431H2O) The formation of ettringite is very fast in this case which results in reduced workability of the cement and therefore requires a retarder. The C2S present in this cement adds to the compressive strength and durability. Mortars made from such cements have comparable compressive strengths and total porosity as compared to Portland cement. The mortar prepared from the Sulfo-Aluminate Belite cement release less quantity of Ca(OH)2 on hydration which helps in reducing the porosity of concrete. The higher content of gypsum in the Sulfo-Aluminate Belite cement also decrease the carbonation of concrete. The Sulfo-Aluminate Belite cement exhibits better protective for the steel reinforcement corrosion.

Another advantage of this cement clinkers is that it requires less electrical energy in cement grinding. Since it requires less amount of limestone in the kiln mix, large quantity of industrial by-products such as fly ash, LD slag, red mud etc can be utilised as raw materials. Phospho-gypsum and flue gas desulfurisation gypsum can replace entirely the requirement of natural gypsum for production of these cements. Further, it has also been experimented that the bottom ash from the thermal power plant can be used as the raw material for production of Sulfo-Aluminate Belite cement as this material has little use at present and increasingly piling up in thermal power plants. Manufacture of limestone calcined clay cement: This is a new development based on researches carried out by Karen Scrivener?s lab at the Swiss Federal Institute of Technology (EPFL) at Lausanne in Switzerland. This technology which is named as LC3 technology looks to be very promising for India considering the saving of clinker in making such cements. It is reported that a composition of 50 per cent clinker ,30 per cent calcined clay, 15 per cent limestone and 5 per cent gypsum gives a product which has equivalent performance as OPC.

IIT Delhi, IIT Madras and Tara (Technology and action for rural development) has tied up with EPFL to develop LC3 with Indian calcined clays and limestones. J.K.Laxmi Jhazzar unit has carried a commercial production of LC3. Plants would need only a calciner for calcining clay as an additional equipment for manufacturing LC3. It is claimed that LC3 can give good performance even with low grade limestone and calcined clays made from poor quality clays at the finish grinding stage. Extensive research is needed to prove the point whether this product can reduce the consumption of Indian cement grade limestone and enable use of large deposits of low grade limestone and over burden clays accumulating in the mines of cement plants. Reactive belite cement: Most of the clinkers manufactured in India are predominantly belitic in nature. Efforts are needed to activate the belite phase in a cost effective manner so as to achieve similar performance as C3S rich clinker and also make finish grinding easier. More research efforts are necessary in this area as this could result in conserving our limited high grade limestone deposits.

Customer education and use of right cement for an application
Indian cement customer especially in the rural regions need extensive education to use the right type of cement for a particular application. For eg. 33 grade OPC is more than sufficient for general construction but customers use 43 grade. The contention is that one can use less cement if it of higher strength. This concept is technically detrimental to concrete. Also in many regions there is an apathy to use PPC and more so in Government projects which is a waste of natural resources . Masonary cements are not in vogue in the country and plastering also is done by 43 grade. This has to be taken up as a national movement with the participation of R&D organisations and the industry. When we use more of lower grade cements and blended cements we are ultimately conserving our reserves of cement grade limestones.

Conclusions
From the above study it can be concluded that there is an urgent need for detailed exploration of limestone deposits in India to establish more limestone reserves from the existing resources as per UNFC classification. Systematic mine planning and multi-mine scheduling is essential to maximise the use of quarry rejects. This should be the thrust area for immediate implementation. Remote Quarry Management especially for plants in a group can prove to be the best business model for mining management in Indian Cement Industry. This model uses the concept of utilising an external expert with all modern IT-enabled services supported by state of art mining software to monitor mining operations. More studies on cost effective dry beneficiation techniques for enrichment of low grade limestone is essential.

The encouragement for production of reactive belite cement, Sulfo-aluminate (C4A3S) belite cement and LC3 in India will provide better solutions for conserving high grade limestone deposits in a sustainable manner. Presently Sulpho-aluminate belite cements are produced commercially in many countries for various applications successfully. More over these cements have immense potential for utilisation of low grade limestone as well as various industrial wastes for manufacture and they are eco-friendly as they release much less CO2 in production as compared to Portland cements. Cements using less and less clinker component needs to be promoted in the country.

Acknowledgement
The authors are thankful to AKS University, Satna management to provide all the support and permission to publish this article.

References
1.Reports of the Working Group on Cement Industry for XII Five Year Plan: Department of Industrial Policy and Promotion, Ministry of Commerce and Industry, Govt of India ( December 2011).
2.Performance of Sulfo-aluminate belite cement with high C4A3S Content: Ivan Janotka, L?udovitKrajci, Subhash C Manjumdar : Ceramic ?Silikaty 31 (2) 74-81 (2007).
3.Synthesis of Calcium Sulfoaluminate Cements from Al2O3-Rich by products from Aluminium Industry. Milena Marro, Maria Lucia Pace, AnotonioTelesica and Gian Lorenzo Valenti: Second International Conference on Sustainable Construction Materials and Technologies: 28-30 June, 2010 UniversitaPolitecnicadella Marche, Ancona, Italy.
4.Beneficiation studies of the Limestone of Malkhed Areas, Gulbarga District, Karnataka: Chinnaiah, Sunil Kumar R K, Basavarajappa H T and Madesh P. International Journal of Earth Science and Engineering: Volume 05, No.01 : February 2012: pp 186-192.
5.Hydrating Behaviour of Activated Belite Sulfoaluminate Cements : Aranda, M A G., Cuberos, A J M., Cuesta A., Alvarez-Pinazo, De la , A G.
6.Beneficiation studies on low grade limestone of Shahabad Area, Shahabad, Gulbarga District, Karnataka: MR Patil and M V Rudramuniyappa : Proceedings of the XI International Seminar on Mineral Processing Technology (MPT-2010): pp 725-729.
7.Remote Quarry Management- S.S. Rawat and P.K.Sarkar, Holtec Consulting Pvt. Ltd.
Around 95% of cement grade limestone deposits are concentrated in 10 states, although the cement grade limestone is occurring in 23 States in smaller quantities.
In India most of the cement plants are operating on heterogeneous intricate limestone deposits with the result that mine reject generation is high..

Authors: HKN Bhattacharjee and GC Mishra of AKS University, Satna (Madhya Pradesh), India.

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Concrete

Balancing Demand and Sustainability

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ICR discusses India’s rapid advances in renewable energy, on track to exceed its 2030 targets, even as the rising energy demands challenge complete reliance on sustainable sources.

The cement industry, a cornerstone of infrastructure development, has long been associated with high emissions, particularly of CO2. This sector alone is responsible for approximately 8 per cent of global carbon dioxide emissions, primarily due to the energy-intensive processes of clinker production and calcination. Beyond carbon emissions, cement production also generates particulates, nitrogen oxides (NOx), sulphur oxides (SOx), and other pollutants, contributing to environmental degradation and health risks. With the global push towards sustainable practices and carbon neutrality, addressing emissions in the cement industry has become imperative.
According to Climate Change Performance Index, India ranks 7 in 2024. India receives a high ranking in the GHG Emissions and Energy Use categories, but a medium in Climate Policy and Renewable Energy, as in the previous year. While India is the world’s most populous country, it has relatively low per capita emissions. Data shows that in the per capita GHG category, the country is on track to meet a benchmark of well below 2°C.
India’s situation underscores the complexity of transitioning to sustainable energy systems in the face of rising and fluctuating energy needs. International support is crucial for India to access advanced technologies, financial resources, and best practices that can accelerate its transition to a sustainable energy future. Our analysis shows that with current policies, India will overachieve its conditional NDC targets of achieving 50 per cent non-fossil capacity by 2030, so it could set stronger targets. India has ambitious renewable energy plans as outlined in the National Electricity Plan 2023 (NEP2023) aiming for a share of installed capacity of 57 per cent and 66 per cent in 2026-27 and 2031-32, respectively. Share of renewable energy capacity in India reached 44 per cent, ranked fourth in the world in renewable energy capacity installations in 2023, after China, the US and Germany. The NEP2023 is reflected in the lower bound of our current policy and action pathway.
India has seen a steady increase in renewable energy deployment, including both utility-scale and rooftop solar, leading to the share of coal capacity dropping below 50 per cent for the first time. However, this increase in renewable energy capacity is barely able to keep up with the surging demand. As a result, the electricity generation share of renewable energy, including large hydro, remains at around 18 per cent, showing no improvement since last year. Investment in renewable energy projects in India are projected to increase by over 83 per cent to around USD 16.5 bn in 2024, with fossil fuel companies also diversifying their investments into the renewable sector. Despite this, India has not committed to phasing out coal power or fossil gas.
The National Electricity Plan indicated a temporary halt in coal capacity addition, but current under-construction capacity exceeds the threshold stated in these plans. While new gas power projects have been abandoned, the utilisation of existing gas power plants has increased to meet energy demand driven by severe heat stress.

Understanding Emissions in Cement Production
Primary Sources of Emissions: Cement production emissions stem mainly from three sources: calcination, fuel combustion, and electricity use. During calcination, limestone is heated to produce clinker, releasing CO2 as a by-product. This process alone accounts for roughly 60 per cent of emissions in cement manufacturing. The remaining emissions result from burning fossil fuels in kilns to achieve the high temperatures needed for calcination and from electricity consumption across production stages.
Raju Ramchandran, SVP Manufacturing (Cluster Head – Central), Nuvoco Vistas, says, “We consistently track air emissions from fuel combustion in our cement manufacturing and power generation operations. The burning of fossil fuels releases pollutants such as Oxides of Sulphur (SOx), Oxides of Nitrogen (NOx), and Particulate Matter (PM), which require stringent monitoring.”
“We ensure compliance with regulatory standards by using the Continuous Emission Monitoring System (CEMS) to monitor these emissions. For the FY 23-24, both our stack and fugitive emissions have stayed within the permissible limits set by Pollution Control Boards. Moreover, our ongoing monitoring of fugitive emissions ensures that we meet the prerequisite air quality standards,” he adds.
In addition to CO2, the cement industry releases various pollutants that pose risks to air quality and public health. These include particulate matter, NOx, and SOx, which can lead to respiratory and cardiovascular issues, acid rain, and ecosystem imbalances.
Governments worldwide are setting increasingly stringent regulations to curb industrial emissions. Standards such as the EU Emissions Trading System and India’s National Action Plan on Climate Change encourage cement manufacturers to adopt cleaner technologies. Many countries now impose limits on NOx, SOx and particulate emissions, with the aim of minimising the industry’s environmental impact.

Challenges in Reducing Emissions
High carbon intensity of cement production: Cement’s high carbon intensity largely stems from the chemical reactions involved in transforming limestone into clinker, making emissions difficult to reduce without altering core processes. Additionally, achieving the necessary kiln temperatures requires significant energy, often derived from coal or natural gas.
Operational limitations: Altering the traditional cement production process can compromise the quality and durability of the end product. Adapting existing production lines for lower emissions involves extensive R&D and technical trials to ensure the finished cement meets industry standards.
Financial constraints: The cost of implementing green technology is high, creating economic challenges, particularly for smaller cement manufacturers. Equipment upgrades, energy-efficient kilns, and carbon capture facilities require considerable investment, which many companies find difficult to justify without strong financial incentives.
Balancing market demands and environmental goals: With global infrastructure demands rising, the cement industry faces pressure to meet growing production needs while simultaneously working to reduce emissions. Balancing these competing demands requires innovation, efficient resource management, and support from stakeholders.

Technological Innovations for Emission Reduction
Alternative fuels and energy sources: One of the most effective ways to reduce emissions is by replacing fossil fuels with alternatives like waste-derived fuels, biomass, or biofuels. Some manufacturers are incorporating solar and wind energy to power auxiliary processes, further reducing reliance on traditional energy sources.
Sudhir Pathak, Head- Central Design & Engg (CDE), QA, Green Hydrogen, Hero Future Energies, says, “The cement industry is one of the largest consumers of grid power (Scope 2) and also a guzzler of in-process fossil CO2 (Scopem1) including process-based CO2 through limekilns. Decarbonisation can be achieved only up to 50 per cent to 60 per cent through plain hybrid solar and wind. However, for achieving balance 40 per cent, storage is essential, be it chemical or mechanical. Today, HFE is ready to provide such bespoke storage solutions as is evident through several complex RTC tenders that we have won in the last 6-8 months floated by agencies like SECI, NTPC and SJVN. These include tenders for FDRE projects, peak power, load following, etc. Further, regarding green hydrogen and its derivatives, we are ready to apply these for decarbonising industrial heating and mobility.”
Carbon Capture and Storage (CCS): CCS technology captures emissions at the source, storing CO2 to prevent it from entering the atmosphere. Recent advancements in CCS technology make it a viable option for large-scale cement plants, although high costs and infrastructure requirements remain obstacles to widespread adoption.
Clinker Substitution: Reducing clinker content is a promising method for emission reduction, achieved by using supplementary cementitious materials (SCMs) such as fly ash, slag, and calcined clay. These materials not only reduce CO2 emissions but also enhance the durability and performance of cement. SCMs are gradually becoming industry-standard components, especially in eco-friendly and green cement products.
Rajesh Kumar Nayma, Assistant General Manager – Environment, Wonder Cement, says, “The use of AFR plays a critical role in our strategy to reduce the environmental footprint of cement production. By substituting traditional fossil fuels with waste-derived alternatives like biomass, refuse-derived fuel (RDF) and industrial by-products, we significantly lower CO2 emissions and reduce the demand for natural resources. The utilisation of supplementary cementitious materials (SCMs), such as fly ash, helps in reducing clinker consumption, which is a major source of carbon emissions in cement production. This not only decreases our reliance on energy-intensive processes but also promotes waste recycling and resource efficiency. AFR adoption is an integral part of our commitment to the circular economy, ensuring that we minimise waste and optimise the use of materials throughout the production cycle, ultimately contributing to a more sustainable and eco-friendly cement industry.”
“WCL is exploring transitioning from fossil fuels to cleaner alternatives like biofuels or hydrogen or RDF/plastic waste/other hazardous waste. Till date, 5 per cent TSR has been achieved, while the intent is to achieve more than 20 per cent TSR. WCL is utilising the hazardous and other waste as an alternative fuel or raw material. We have used more than 3 lakh metric tonne of hydrogen waste and other waste in FY-2023-24,” he adds.
Improving energy efficiency is critical for emissions reduction. Technologies like high-efficiency kilns, heat recovery systems, and process optimisation techniques are helping manufacturers achieve more output with less energy. These measures reduce the carbon footprint while lowering operational costs.

The Role of SCMs
SCMs serve as partial replacements for clinker, providing a dual benefit of reduced carbon emissions and improved product resilience. The use of materials like fly ash and slag also helps mitigate industrial waste, contributing to a circular economy. Fly ash, slag, and silica fume are among the most widely used SCMs. Each has unique properties that contribute to cement’s strength, workability, and durability. By incorporating SCMs, manufacturers can produce cement with a lower environmental footprint without compromising quality.
While SCMs are effective, several obstacles hinder their widespread adoption. Supply chain constraints, material variability, and lack of technical standards are challenges that manufacturers face. Additionally, geographic limitations impact access to certain SCMs, creating disparities in their usage across regions.

Policy and Industry Collaboration
Policies play a critical role in driving green transitions within the cement industry. Carbon credits, tax incentives, and funding for R&D are some measures governments have introduced to support emission reduction. India’s Perform, Achieve, and Trade (PAT) scheme is an example of a policy incentivising industrial energy efficiency.
Collaborations between government entities, private corporations, and research institutions foster innovation and accelerate the adoption of sustainable practices. Partnerships can also help address funding gaps, allowing companies to explore new technologies without bearing the full financial burden.
International frameworks such as the Paris Agreement and industry-led efforts like the Global Cement and Concrete Association (GCCA) are setting targets for sustainable cement production. These initiatives encourage the sector to adopt environmentally friendly practices and set a roadmap toward achieving net-zero emissions.

Towards a Net-Zero Future
Reaching net-zero emissions is an ambitious but necessary goal for the cement industry. Realistic targets, set with interim milestones, allow companies to gradually transition to greener processes while maintaining production efficiency. Continued investment in R&D is crucial for discovering new methods of emission reduction. Emerging technologies such as carbon-negative materials, alternative binders, and low-carbon clinkers hold promise for the future, potentially transforming cement production into a more sustainable process.
Increasingly, consumers and investors are prioritising sustainability, placing pressure on companies to reduce their environmental impact. This shift in consumer sentiment is driving the cement industry to adopt green practices and focus on transparency in emissions reporting.

Conclusion
The journey toward reducing environmental impact in the cement industry is complex and multifaceted, requiring a combination of innovation, policy support, and industry collaboration. By adopting alternative fuels, implementing carbon capture technology, integrating SCMs, and improving energy efficiency, the industry can take significant strides in minimising its carbon footprint. Achieving sustainability in cement production is essential not only for the industry’s future but also for the planet’s well-being. Together, industry players, policymakers, and consumers can support the transition to a net-zero future, ensuring that cement remains a vital yet sustainable component of global infrastructure.

– Kanika Mathur

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Concrete

Red River Formation in Kiln Operations

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Dr SB Hegde, Professor, Jain College of Engineering and Technology, Hubli, and Visiting Professor, Pennsylvania State University, USA, helps us understand the red river formation in cement kiln operations, its causes, impacts and mitigation strategies.

Red river formation in cement kilns, where molten clinker flows uncontrollably in the cooler, is a costly problem for cement plants. The phenomenon not only affects clinker quality but also leads to significant operational disruptions, increased energy consumption and accelerated wear on kiln refractory bricks. Understanding the factors that cause red river formation and implementing strategies to prevent it are critical to maintaining operational efficiency and clinker quality.
This paper explores the causes of red river formation, the operational impacts it has on kiln performance, and the various mitigation strategies that cement plants can adopt. Additionally, safety considerations associated with the prevention and handling of red river formation are discussed, with practical insights from case studies of successful plant interventions in India and globally.

Causes of red river formation
Red river formation is primarily caused by improper kiln operations, including fluctuating kiln temperatures, oxygen levels, and cooler inefficiency. The following parameters are essential contributors:
Kiln temperature: Inconsistent temperature control in the kiln’s burning zone, often exceeding 1500°C, creates an imbalance between the solid and molten clinker phases, leading to red river formation. Maintaining temperatures within a more stable range of 1470-1490°C ensures that the clinker remains solid as it moves into the cooler.
Oxygen levels and CO concentrations: Oxygen levels above 2.5 per cent increase the risk of over-combustion, while elevated CO levels above 0.3 per cent indicate incomplete combustion, both contributing to excessive clinker melting. Optimising oxygen levels to 1.8-2.0 per cent minimises the risk.
Raw mix composition: The raw mix plays a vital role in clinker formation. A high liquid phase due to improper ratios of silica, alumina, and iron oxide can lead to excessive melting. Controlling the silica modulus (SM: 2.3-2.7) and alumina modulus (AM: 1.3-1.8) ensures a more stable clinker and reduces the risk of red river formation. If the raw mix is improperly proportioned, red river formation becomes more likely due to high fluxing compounds that melt at lower temperatures.
Kiln speed and torque: Kiln speeds that fluctuate below 3.4 rpm can cause material buildup, while kiln torque exceeding 50-60 per cent indicates stress that can lead to clinker instability.
Cooler efficiency: Inefficiencies in the clinker cooler, with efficiency levels below 78 per cent, can exacerbate red river formation. Clinker that is not cooled properly will remain molten for longer, allowing it to flow uncontrollably. Coolers should maintain exit temperatures between 180-200°C to prevent red river incidents.
Impact on clinker quality and kiln performance
The occurrence of red river has numerous negative impacts on both clinker quality and kiln performance:
Clinker quality: Red river formation results in poor clinker grindability, higher variability in free lime content and inconsistent cement properties. Poor clinker reactivity reduces both early and late strength development in the final cement product.
Increased heat consumption: Red river typically increases specific heat consumption by 3-5 per cent, resulting in higher fuel usage. These inefficiencies can significantly affect the plant’s cost structure, driving up operational expenses.
Refractory damage: The molten clinker accelerates the wear of refractory bricks in the kiln, especially in the burning zone and cooler transition areas. Brick life can decrease by 25-30 per cent, leading to more frequent replacements and higher maintenance costs.
Equipment and instrumentation damage: The uncontrolled molten flow of clinker during red river incidents can damage cooler plates, kiln discharge systems, and even temperature sensors and thermocouples, leading to costly repairs and prolonged downtime.

Mitigation strategies
Mitigating red river formation requires a multi-faceted approach combining operational optimisation, automation and staff training:
Kiln temperature control: Maintaining stable burning zone temperatures in the 1470-1490°C range is key to preventing excessive melting of clinker. Advanced temperature monitoring systems can help regulate temperature fluctuations.
Cooler efficiency optimisation: To ensure proper cooling, cooler efficiency must be maintained at 78-80 per cent, with clinker exit temperatures not exceeding 200°C. Real-time airflow adjustments in grate coolers improve cooling performance, solidifying the clinker at the appropriate stage.
Automation and data analytics: Advanced Process Control (APC) systems using data analytics can monitor critical kiln parameters—such as temperature, oxygen levels, and torque—in real-time, allowing for predictive maintenance and early intervention when red river signs appear. This technology has been implemented successfully in leading plants globally to prevent red river formation.

Indian case studies
Case Study 1: Cement Plant in South India – Optimisation of Kiln Parameters
A cement plant in South India faced recurrent red river issues due to high kiln temperatures and low cooler efficiency. After comprehensive process audits, the plant optimised its kiln temperature to 1480°C, reduced oxygen levels to 1.9 per cent, and upgraded its cooler to an efficiency of 80 per cent. These changes reduced red river incidents by 85 per cent, saving the plant Rs 10 million in energy costs annually and improving clinker quality by
15 per cent.

Case Study 2: Cement Plant in North India – Cooler Upgrade and Automation
A northern India plant increased cooler efficiency from 70 per cent to 78 per cent by installing an advanced grate cooler. This reduced clinker exit temperatures to 190°C, preventing red river formation. Automation systems provided real-time adjustments, decreasing the frequency of incidents by 75 per cent and saving `12 million annually.

Global Case Studies
Case Study 1: European Plant – Automation Success
A German cement plant, experiencing red river issues due to fluctuating oxygen levels, installed an advanced data-driven automation system. The system stabilised oxygen at 1.9 per cent and maintained kiln temperature at 1,475-1,485°C, reducing red river by 90 per cent. Clinker quality improved by 10 per cent, with a reduction in specific heat consumption by 4 per cent.

Case study 2: US Plant – Operator Training and Process Optimisation
A US cement plant reduced red river occurrences by 70 per cent through kiln speed optimisation (3.8 rpm) and comprehensive operator training. Improved monitoring of kiln torque and cooler exit temperatures led to higher cooler efficiency (75 per cent) and an annual savings of $2 million.

Safety Aspects
Safety is a paramount concern in red river incidents. When molten clinker flows uncontrollably, it poses a significant risk to personnel working near the kiln and cooler areas.

To mitigate these risks:

  • Clearance zones: Kiln and cooler areas should have strict clearance zones for personnel when red river incidents are detected.
  • Protective gear and training: Personnel should be equipped with proper protective equipment (PPEs) and trained to handle emergencies involving molten clinker. Emergency shutdown procedures should be well-documented and rehearsed.
  • Automation and early warning systems: Automation can provide early warning systems that alert operators to potential red river formation before it becomes critical, ensuring safe intervention.

Conclusion
Red river formation remains a major operational challenge for cement plants, but it can be effectively mitigated through proper kiln temperature control, cooler efficiency optimisation and the use of advanced automation systems.
The case studies highlight the importance of process improvements and staff training in reducing red river occurrences, improving clinker quality, and lowering operational costs. Additionally, safety
measures must be prioritised to protect personnel from the risks posed by molten clinker. By incorporating these strategies, cement plants can ensure consistent kiln performance and enhanced operational efficiency.

References
1. Duda, W. H. (1985). Cement Data Book. International Process Engineering in the Cement Industry. Bauverlag GmbH.
2. Javed, I., & Sobolev, K. (2020). “Use of Automation in Modern Cement Plants.” Cement and Concrete Research, 130, 105967.
3. Tamilselvan, P., & Kumar, R. (2023). “Optimisation of Kiln and Cooler Systems in Indian Cement Plants.” Indian Cement Review, 34(7), 42-48.
4. Martin, L. (2019). “Case Studies of Red River Mitigation in European Cement Plants.” International Journal of Cement Production, 12(2), 63-78.
5. Schorr, H. (2021). “Advanced Process Control in Cement Manufacturing.” Cement International, 19(3), 30-37.
6. Singh, V. K., & Gupta, A. (2022). “Impact of Raw Mix on Clinker Formation and Kiln Operations.” Global Cement Magazine, 14(4), 22-29.

About the author: Dr SB Hegde brings over thirty years of leadership experience in the cement industry in India and internationally. He has published over 198 research papers and holds six patents, with four more filed in the USA in 2023. His advisory roles extend to multinational cement companies globally and a governmental Think Tank, contributing to research and policy. Recognised for his contributions, he received the ‘Global Visionary Award’ in 2020 from the Gujarat Chambers of Commerce and Industry.

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Concrete

SCMs encourage closed-loop systems

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As the cement industry prioritises sustainability and performance, Supplementary Cementitious Materials (SCMs) are redefining standards, explains Tushar Khandhadia, General Manager – Production, Udaipur Cement Works.

What role do supplementary cementitious materials (SCMs) play in enhancing the performance and sustainability of cement and concrete?
SCMs play a crucial role in enhancing the performance and sustainability of cement and concrete. These materials are added to concrete to improve its properties such as strength, durability, and workability, as well as to reduce the environmental impact of cement production. The addition of SCMs to cement reduces the amount of Portland cement required to manufacture concrete, reducing the carbon footprint of the concrete. These materials are often industrial waste products or by-products that can be used as a replacement for cement, such as fly ash, slag and silica fume.
SCMs also reduce the amount of water required to produce concrete, which reduces the environmental impact of concrete production. This is achieved through their ability to improve the workability of concrete, allowing the same amount of work to be done with less water.
In addition, SCMs improve the durability of concrete by reducing the risk of cracking and improving resistance to chemical attack and other forms of degradation.

How has your company integrated SCMs into its production process, and what challenges have you encountered?
The integration of SCMs into cement and concrete production may pose certain challenges in the areas of sourcing, handling and production optimisation.

  • Sourcing: Finding an adequate and reliable supply of SCMs can be a challenge. Some SCMs, such as fly ash and slag, are readily available by-products of other industrial processes, while others such as silica fume or metakaolin may be more difficult to source.
  • Handling: The storage, handling, and transportation of SCMs require special considerations due to their physical and chemical properties. For instance, some SCMs are stored in moist conditions to prevent them from drying out and becoming airborne, which could pose a safety risk to workers.
  • Production optimisation: The addition of SCMs into the mix may require adjustments to the production process to achieve the desired properties of cement and concrete. For example, the use of SCMs may affect the setting time, workability, strength gain, and other properties of the final product, which may require reconfiguration of the production process.
  • Quality control: The addition of SCMs may introduce variability in the properties of cement and concrete, and rigorous quality control measures are necessary to ensure the final product meets the required specifications and standards.

Proper planning, handling and production optimisation are essential in overcoming the challenges encountered during the integration process.

Can you share insights on how SCMs such as fly ash, slag and silica fume impact the durability and strength of concrete in different environmental conditions?

  • Fly ash is a by-product of coal combustion and is widely used as an SCM in the production of concrete. When added to concrete, fly ash reacts with the calcium hydroxide present in the concrete to form additional cementitious materials, resulting in improved strength and durability. Fly ash increases the durability of concrete by improving its resistance to sulphate and acid attacks, reducing shrinkage and decreasing the permeability of concrete. Fly ash also enhances the workability and pumpability of concrete while reducing the heat of hydration, which reduces the risk of thermal cracking. In cold climates, fly ash helps to reduce the risk of freeze-thaw damage.
  • Slag is a by-product of steel production and is used as an SCM because of its high silica and alumina content. When added to concrete, slag reacts with the calcium hydroxide present in the concrete to form additional cementitious materials, resulting in improved strength and durability. Slag increases the durability of concrete by improving its resistance to sulphate and acid attacks, reducing shrinkage and improving the strength of concrete over time. Slag also enhances the workability of concrete, reduces the heat of hydration, and improves the resistance of concrete to chloride penetration.
  • Silica fume is a by-product of the production of silicon and ferrosilicon alloys and is used as an SCM because of its high silica content. When added to concrete, silica fumes react with the calcium hydroxide present in the concrete to form additional cementitious materials, resulting in improved strength and durability. Silica fume increases the durability of concrete by improving its resistance to sulphate and acid attacks, reducing permeability, and improving abrasion resistance. Silica fume also enhances the workability of concrete, reduces the heat of hydration, and improves the resistance of concrete to chloride penetration.

Overall, the use of SCMs such as fly ash, slag and silica fume can significantly improve the durability and strength of concrete in different environmental conditions. Their impact on concrete varies depending on the availability, physical and chemical properties of the specific SCM being used and proper testing and engineering analysis should be done for each mix design in order to optimise the final product.

With the global push for sustainability, how do SCMs contribute to reducing the carbon footprint of cement production?
SCMs provide an environmentally friendly alternative to traditional Portland cement by reducing the amount of clinker required to produce cement. Clinker is the main ingredient in Portland cement and is produced by heating limestone and other raw materials to high temperatures, which releases significant GHG emissions. Thus, by using SCMs, less clinker is required, thereby reducing GHG emissions, energy use and the environmental impact of cement production. Some SCMs such as fly ash and slag are by-products of other industrial processes, meaning that their use in cement production reduces waste and enhances resource efficiency. Moreover, the use of SCMs can enhance the properties of concrete, thereby increasing its durability and service life which helps to further reduce the overall embodied carbon of the structure.
In short, the use of SCMs contributes to reducing the carbon footprint of cement production by improving the efficiency of resource utilisation and reducing greenhouse gas (GHG) emissions during the production process. This has led to an increased demand for SCMs in the construction industry, as environmental concerns and sustainable development goals have become more prominent factors in the selection of building materials.

What strategies or innovations has your company adopted to ensure a consistent and reliable supply of SCMs, given their reliance on industrial by-products?

  • Developing partnerships with suppliers: Many cement and concrete manufacturers establish long-term partnerships with suppliers of SCMs. These partnerships provide a reliable supply of high-quality SCMs, improve supply chain efficiency, and often provide access to new sources of SCMs.
  • Advanced SCM processing techniques: Many companies are investing in advanced processing techniques to unlock new sources of high-quality SCMs. Advanced processing techniques include new separation processes, calcination techniques, and chemical activation methods.
  • Alternative SCM sources: Many companies are exploring alternative SCM sources to supplement or replace traditional SCMs. Examples include agricultural by-products such as rice hull ash or sugar cane bagasse ash, which can be used in place of fly ash.
  • Quality control measures: Strict quality control measures are necessary to ensure consistent quality of SCMs. Many companies use advanced testing methods, such as particle size analysis, chemical analysis, and performance testing, to validate the quality of SCM materials used in production.
  • Supply chain diversification: Diversifying suppliers and SCM sources is another way to ensure a reliable supply. This reduces the risk of supply chain disruptions caused by factors such as natural disasters, market changes, or geopolitical risks.

The strategies and innovations adopted to ensure a consistent and reliable supply of SCMs include establishing long-term partnerships with suppliers, investing in advanced processing techniques, exploring alternative SCM sources, implementing strict quality control measures, and diversifying supply chains. By implementing these approaches, we ensure that use of SCMs in cement production is an effective and viable solution for reducing the environmental impact of operations

How does the use of SCMs align with your company’s broader goals around circular economy and resource efficiency?
Here are some ways in which the use of SCMs supports these goals:

  • Reducing waste: The use of SCMs, such as fly ash and slag, diverts significant quantities of industrial waste from landfills, turning it into a valuable resource that can be used in construction. This helps to reduce waste and conserve natural resources.
  • Reducing carbon emissions: Cement production is a significant contributor to greenhouse gas emissions, and the use of SCMs can significantly reduce the amount of cement required in concrete mixtures. This helps to reduce the carbon footprint of construction activities and move towards a low-carbon economy.
  • Enhancing resource efficiency: The use of SCMs can reduce the demand for raw materials, energy, and water in the production of concrete. This not only conserves natural resources but also reduces the costs associated with the extraction, transportation and processing of these materials.
  • Closing the loop: SCMs encourage closed-loop systems in the construction sector, where waste materials from one process become input materials for another. This can improve the efficiency and sustainability of the construction industry.
  • Supporting sustainable design practices: The use of SCMs can support sustainable design practices by improving the durability and performance of structures while also reducing their environmental impact. This supports a circular approach to design, construction and operation of buildings and infrastructure
    that improves their social, economic and environmental sustainability.

What future trends or developments do you foresee in the use of SCMs within the cement industry?
Future trends in the use of SCMs within the cement industry are likely to focus on: increased utilisation of diverse waste-derived SCMs, development of new SCM sources to address potential shortages, advanced characterisation techniques to optimise SCM blends and data-driven approaches to predict and optimise SCM usage for reduced carbon footprint and improved concrete performance; all driven by the growing need for sustainable cement production and stricter environmental regulations.
Key aspects of this trend include:

  • Expanding SCM sources: Exploring a wider range of industrial byproducts and waste materials like recycled concrete aggregate, activated clays and certain types of industrial minerals as potential SCMs to reduce reliance on traditional sources like fly ash, which may become increasingly limited.
  • Advanced material characterisation: Utilising sophisticated techniques to better understand the chemical and physical properties of SCMs, allowing for more precise blending and optimisation of their use in cement mixtures.
  • Data-driven decision making: Implementing machine learning and big data analysis to predict the performance of different SCM combinations, allowing for real-time adjustments in cement production based on available SCM sources and desired concrete properties.
  • Focus on local sourcing: Prioritising the use of locally available SCMs to reduce transportation costs and environmental impact.
  • Development of new SCM processing techniques: Research into methods to enhance the reactivity and performance of less readily usable SCMs through processes like activation or modification.
  • Life cycle analysis (LCA) integration: Using LCA to assess the full environmental impact of different SCMs and optimise their use to minimise carbon emissions throughout the cement production process.
  • Regulatory frameworks and standards:Increased adoption of building codes and industry standards that promote the use of SCMs and set targets for reduced carbon emissions in cement production.

– Kanika Mathur

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